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基于弱相互作用力的共混型吸附剂去除六价铬离子

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本研究采用聚乙二醇(PEG)与单宁酸(TA)的氢键和范德华力等弱相互作用力制备了一种新型混凝剂.在Fe2+的辅助下,Cr(Ⅵ)可在中性条件下形成沉淀.Cr(Ⅵ)质量浓度在 2h内可由 100 mg/L降至<0.1 mg/L.且Fe2+的用量缩减为目前工业技术的1/3.去除过程涉及氧化还原-螯合、电荷相互作用和物理包裹等多种相互作用.由于反应条件温和、去除效率高,有望成为一种具有较大应用前景的新型除铬技术.
Blended Adsorbents Based on Weak Interaction Forces for Removing Hexavalent Chromium Ions
This study prepared a new type of coagulant using weak interactions such as hydrogen bonding and van der Waals forces between polyethylene glycol(PEG)and tannic acid(TA).With the assistance of Fe2+,Cr(VI)can form precipitates under neutral conditions.The mass concentration of Cr(VI)can be reduced from 100 mg/L to<0.1 mg/L within 2 hours.And the amount of Fe2+ used has been reduced to one-third of the current industrial technology.The removal process involves various interactions such as oxidation-reduction chelation,charge interaction,and physical encapsulation.Due to mild reaction conditions and high removal efficiency,it is expected to become a new type of chromium removal technology with great application prospects.

coagulationhexavalent chromium removalpolyethylene glycoltannic acidweak interaction

罗越峰、施鹏、陈俊良、喻安平、冯信鑫

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西南石油大学化学化工学院, 四川 成都 610500

混凝 六价铬去除 聚乙二醇 丹宁酸 弱相互作用力

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(1)
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