山西化工2024,Vol.44Issue(1) :54-55,61.DOI:10.16525/j.cnki.cn14-1109/tq.2024.01.018

X荧光光谱法测定有机肥中的金属元素砷、铬、铅

Determination of Metal Elements Arsenic,Chromium,and Lead in Organic Fertilizers by X-ray Fluorescence Spectroscopy

周小淋
山西化工2024,Vol.44Issue(1) :54-55,61.DOI:10.16525/j.cnki.cn14-1109/tq.2024.01.018

X荧光光谱法测定有机肥中的金属元素砷、铬、铅

Determination of Metal Elements Arsenic,Chromium,and Lead in Organic Fertilizers by X-ray Fluorescence Spectroscopy

周小淋1
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作者信息

  • 1. 甘肃省有色金属地质勘查局张掖矿产勘查院, 甘肃 张掖 734000
  • 折叠

摘要

为了快速、准确地分析有机肥中砷、铬、铅的含量,更好地为农业土壤污染防治服务,营造一个健康的农业生态环境,保证农产品的安全性.采用X荧光光谱法测定有机肥中的砷、铬、铅,测定结果中砷、铬、铅的精密度(RSD)分别为 2.5%~6.2%、2.6%~5.6%、3.4%~7.8%;方法检出限分别为 0.5 mg/kg、3.3 mg/kg、Pb为 1.8 mg/kg,其满足质量规范要求.与标准NY 525-2021 作方法比对,数据一致性好,可靠.充分解决了操作繁琐、测定周期长、精密度差、成本高、污染环境等问题,值得研究借鉴,具有一定的应用推广价值.

Abstract

In order to quickly and accurately analyze the content of arsenic,chromium,and lead in organic fertilizers,better serve the prevention and control of agricultural soil pollution,create a healthy agricultural ecological environment,and ensure the safety of agricultural products,arsenic,chromium,and lead in organic fertilizers were determined by X-ray fluorescence spectroscopy.The precision(RSD)of arsenic,chromium,and lead were 2.5%to 6.2%,2.6%to 5.6%,and 3.4%to 7.8%,respectively.The detection limits of the method are 0.5 mg/kg,3.3 mg/kg,and Pb is 1.8 mg/kg,which meet the quality specification requirements.Compared with the standard NY 525-2021 method,the data consistency is good and reliable.It fully solves the problems of cumbersome operation,long measurement cycle,poor precision,high cost,and environmental pollution,and is worthy of research and reference,with certain application and promotion value.

关键词

粉末压片/XRF////有机肥

Key words

powder tablet pressing/XRF/arsenic/chromium/lead/organic fertilizer

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基金项目

国家科技支撑计划基金项目(2007BAD89B17)

甘肃省科技计划项目(1006NCXG012)

出版年

2024
山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
参考文献量10
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