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低浓度瓦斯燃料重整技术及电化学性能分析

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研究针对低浓度瓦斯在固体氧化物燃料电池中的催化重整作用进行分析.在分析过程中研究将碳氧比例作为主要调控变量,将低浓度瓦斯燃料作为主要催化作用物.首先研究将镍基-氧化钇稳定氧化锆(Ni-YSZ)阳极支撑半电池作为重整催化反应器,对比分析不同碳氧比例下的催化重整反应和燃料成分变化规律.之后研究通过制备固体氧化物燃料电池来分析不同碳氧比例的低浓度瓦斯固体氧化物电池的性能变化.研究结果显示,在碳氧比例不断降低的情况下,甲烷转化率表现出在变化前端有所升高,变化后端有所降低的趋势.同时在低浓度瓦斯固体氧化物电池电化学性能测试中,在 750℃环境下,电池能够在较长时间下稳定提供 0.78 V的电压,并且在这一过程中阳极部分没有明显的积碳生成,兼具效率性与稳定性.
Low Concentration Gas Fuel Reforming Technology and Electrochemical Performance Analysis
This study analyzes the catalytic reforming effect of low concentration gas in solid oxide fuel cells.In the analysis process,the carbon oxygen ratio is studied as the main regulatory variable,and low concentration gas fuel is used as the main catalytic agent.Firstly,a nickel based yttria stabilized zirconia(Ni-YSZ)anode supported half cell was studied as a reforming catalytic reactor,and the catalytic reforming reaction and fuel composition changes under different carbon oxygen ratios were compared and analyzed.Afterwards,the study analyzed the performance changes of low concentration gas solid oxide fuel cells with different carbon oxygen ratios by preparing solid oxide fuel cells.The research results show that as the carbon oxygen ratio continues to decrease,the methane conversion rate shows a trend of increasing at the front end of the change and decreasing at the back end.At the same time,in the electrochemical performance testing of low concentration gas solid oxide batteries,at 750℃,the battery can stably provide a voltage of 0.78 V for a long time,and there is no obvious carbon deposition in the anode during this process,which combines efficiency and stability.

clean energylow concentration gasfuel reformingelectrochemistry

赵琪

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晋能控股集团长治公司马堡煤业有限公司, 山西 长治 046600

清洁能源 低浓度瓦斯 燃料重整 电化学

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(1)
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