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裂化催化剂级配优化后对加氢尾油影响分析

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中国石化海南炼油化工有限公司(以下简称海南炼化)加氢裂化装置于 2017 年大检修期间对原催化剂FF-46 与FC-16B采用器外再生后重新装入反应器并补充新的精制剂FF-66 与裂化剂FC-80.通过FRIPP对催化剂的级配作优化调整后,根据裂化剂FC-80 具有良好的环状烃开环与优异的的芳烃加氢饱和特性,加裂尾油的黏度指数提高了 20,尾油中BMCI值(芳烃指数)降低 8,但加氢后的尾油凝点提高10℃,作为润滑油基础油.下游装置的进一步的临氢异构脱蜡后产品的凝点在-20℃以下,加氢后的产品性能满足要求.
Analysis of the Impact of Optimized Grading of Cracking Catalysts on Hydrogenated Tail Oil
During the 2017 major overhaul of Sinopec Hainan Refining and Chemical Co.,Ltd.(hereinafter referred to as Hainan Refining and Chemical)hydrocracking unit,the original catalysts FF-46 and FC-16B were regenerated outside the reactor and re loaded into the reactor,supplemented with new refining agent FF-66 and cracking agent FC-80.After optimizing and adjusting the catalyst gradation through FRIPP,based on the excellent cyclic hydrocarbon opening and aromatic hydrocarbon hydrogenation saturation characteristics of cracking agent FC-80,the viscosity index of cracked tail oil increased by 20,and the BMCI value(aromatic hydrocarbon index)in the tail oil decreased by 8.However,the pour point of the hydrogenated tail oil increased by 10℃,making it a lubricating base oil.The condensation point of the product after further hydroisomerization dewaxing in the downstream device is below-20℃,and the performance of the product after hydrogenation meets the requirements.

hydrocrackingcatalyst FC-80grading optimizationviscosity indexBMCI value

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中国石化海南炼油化工有限公司, 海南 洋浦 578101

加氢裂化 催化剂FC-80 级配优化 粘度指数 BMCI值

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(4)
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