首页|高熵合金与E-Fenton试剂处理染料废水实验研究

高熵合金与E-Fenton试剂处理染料废水实验研究

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处理染料废水的电芬顿(Electro-Fenton,E-Fenton)技术已经展现出显著的优势.然而,在实际应用中,电极材料的耐用性和腐蚀问题一直是限制其进一步发展的关键因素.为了解决这些问题,并进一步提高降解效率,研究决定采用高熵合金作为阳极,并结合E-Fenton试剂进行实验.目标是以甲基橙为模拟污染物,对染料废水进行降解处理.实验结果显示,在反应进行 5h 后,Al0.3CoCrFe2Ni 高熵合金的最大腐蚀速率仅为 5.94 g/cm2·h.与Al0.3CoCrFe1.7Ni、Al0.3CoCrFe1.3Ni、Al0.3CoCrFe0.9Ni和铁片的腐蚀速率相比,分别降低了 44.17%、63.44%、78.06%和84.59%.Al0.3CoCrFe2Ni和Al0.3CoCrFe1.7Ni合金均出现了Fe2O3 和Fe3O4 的衍射峰.这一研究结果表明,高熵合金与E-Fenton试剂联合处理染料废水的方法,有效地提高了电极材料的耐腐蚀性.这不仅为染料废水的处理提供了新的解决方案,同时也进一步证实了高熵合金在环保领域的应用潜力.
Experimental Study on the Treatment of Dye Wastewater with High Entropy Alloy and E-Fenton Reagent
The electro Fenton(E-Fenton)technology for treating dye wastewater has shown significant advantages.However,in practical applications,the durability and corrosion issues of electrode materials have always been key factors limiting their further development.In order to address these issues and further improve degradation efficiency,the study decided to use high entropy alloys as anodes and conduct experiments in combination with E-Fenton reagents.The goal is to use methyl orange as a simulated pollutant to degrade dye wastewater.The experimental results show that after 5 hours of reaction,the maximum corrosion rate of Al0.3CoCrFe2Ni high entropy alloy is only 5.94 g/cm2·h.Compared with the corrosion rates of Al0.3CoCrFe1.7Ni,Al0.3CoCrFe1.3Ni,Al0.3CoCrFe0.9Ni,and iron sheets,the corrosion rates were reduced by 44.17%,63.44%,78.06%,and 84.59%,respectively.Both Al0.3CoCrFe2Ni and Al0.3CoCrFe1.7Ni alloys exhibit diffraction peaks of Fe2O3 and Fe3O4.This research result indicates that the combination of high entropy alloy and E-Fenton reagent in the treatment of dye wastewater effectively improves the corrosion resistance of electrode materials.This not only provides a new solution for the treatment of dye wastewater,but also further confirms the potential application of high entropy alloys in the field of environmental protection.

E-Fentonhigh entropy alloysdye wastewatermethyl orangecorrosion resistance

焦守峰

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淮北职业技术学院,安徽 淮北 235000

E-Fenton 高熵合金 染料废水 甲基橙 耐腐蚀性

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(6)