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灰熔融对煤焦介电性能及结构的影响

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本文以新疆烟煤为研究对象,制取不同工况下所对应的脱灰前后的煤焦,利用矢量网络分析仪测得煤焦的介电性能,并通过XRD、FT-IR、热重分析对煤焦微观结构及热稳定性进行表征.得出以下结论:当制焦温度在灰熔点以下时,灰分的存在阻碍了煤焦介电性能的发展,这主要是由于灰分可以促进煤焦热解过程中碳的溶损反应,从而破坏了原有的碳层结构,进而使得原煤煤焦的结构有序性较差、热稳定性较弱、石墨化程度较低、介电性能较弱;当制焦温度在灰熔点以上时,灰熔融可以使得煤焦拥有较高的介电性能,这是因为熔融的灰分附着在煤焦表面,能够阻碍煤焦的传质能力,使得煤焦难以形成发达的孔结构,因此原煤煤焦结构有序性较好、热稳定性较强、石墨化程度较高、介电性能较强.
Effect of Ash Melting on the Dielectric Properties and Structure of Coal Chars
Taking Xinjiang bituminous coal as the research object,this paper produced the corresponding coal and coke before and after ash under different working conditions,measured the dielectric performance of coal and coke by using the vector network analyzer,and characterized the microstructure and thermal stability of coal and coke by XRD,FT-IR and thermal weight analysis.The following conclusion is drawn when the coke temperature is below the ash melting point,the presence of ash hinders the development of dielectric properties of coal coke.This is mainly because ash can promote the dissolution reaction of carbon in pyrocoke.Thus destroying the original carbon layer structure.Then,the structure order of raw coal and coal coke is poor,the thermal stability is weak,the graphitization degree is low,and the dielectric performance is weak.When the focusing temperature is above the ash melting point,grey melting can make coal coke have a high dielectric performance.This is because the molten ash attaches to the surface of the coal coke,which can hinder the mass transfer capacity of coal coke,making it difficult to form a developed pore structure.Therefore,the raw coal and coal coke structure has good order,strong thermal stability,high degree of graphitization,and strong dielectric performance.

ash meltingcoal charsdielectric propertiesstructure

刘元春、严鹏航

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机械工业出版社,北京 100037

北京国电富通科技发展有限责任公司,北京 100070

南瑞集团(国网电力科学研究院)有限公司,江苏 南京 211106

灰熔融 煤焦 介电性能 结构

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(6)