首页|电解液添加剂中氟代碳酸乙烯酯、氯代碳酸乙烯酯的应用

电解液添加剂中氟代碳酸乙烯酯、氯代碳酸乙烯酯的应用

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在电池的制造生产中,氟代碳酸乙烯酯(FEC)、氯代碳酸乙烯酯(CEC)在作为添加剂用于电解液后,其电解液的电化学窗口等性能可以得到提高,进而提高电池在循环多次后的容量保持率.为此,本文首先进行氯代碳酸乙烯酯的合成研究,探讨不同指标对产品制造的影响和生产不足.其次,将氟代碳酸乙烯酯作为电解液添加剂,应用恒流充放电、循环伏安(CV)和电化学阻抗谱(EIS)等方法,研究对LiNi0.5Mn1.5O4/Li、电解液的电化学窗口、Li/MCMB半电池的性能影响.最后经过实验讨论,氟代碳酸乙烯酯能有效作为电解液添加剂并应用在电池中,利于提高电池的整体质量.
Application of Fluorinated Ethylene Carbonate and Chlorinated Ethylene Carbonate in Electrolyte Additives
In the manufacturing and production of batteries,fluoroethylene carbonate(FEC)and chloroethylene carbonate(CEC),when used as additives in electrolytes,can improve the electrochemical window and other performance of the electrolyte,thereby improving the capacity retention rate of the battery after multiple cycles.Therefore,this article first conducts a study on the synthesis of vinyl chlorocarbonate,exploring the impact of different indicators on product manufacturing and production deficiencies.Secondly,using fluoroethylene carbonate as an electrolyte additive,the effects of constant current charge discharge,cyclic voltammetry(CV),and electrochemical impedance spectroscopy(EIS)on LiNi0.5Mn1.5O4/Li,the electrochemical window of the electrolyte,and the performance of Li/MCMB half cells were studied.Finally,through experimental discussion,it was found that fluoroethylene carbonate can effectively serve as an electrolyte additive and be applied in batteries,which is beneficial for improving the overall quality of batteries.

fluoroethylene carbonateelectrolyte additivesapplication exploration

龙昊天

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中化环境科技工程有限公司,辽宁 沈阳 110031

氟代碳酸乙烯酯 电解液添加剂 应用探讨

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(6)