首页|Ag1.8Mn8O16/MWCNTs杂化材料的制备及其电催化氧还原性能

Ag1.8Mn8O16/MWCNTs杂化材料的制备及其电催化氧还原性能

Synthesis of Ag1.8Mn8O16/MWCNTs Hybrid Materials and Their Electrocatalytic Performance for Oxygen Reduction Reaction

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克服动力学缓慢和解决电荷传输能力差是ORR电催化剂在实际化应用过程中必须要考虑到的两个重要问题.据此,本文使用MWCNTs作为良好的导电载体,采用一种绿色、经济和易得的合成方法成功地制备了Ag1.8Mn8O16/MWCNTs杂化材料,在碱性介质中该杂化材料展现出优异的电催化氧还原活性,起始电位和半波电位分别达到 1.00 V和0.79 V,tafel斜率低至 131.5 mV/dec,动力学电流密度高达 8.8 mA/cm2@0.75 V.活性的增强归因于Ag1.8Mn8O16 与MWCNTs之间协同作用的结果.本研究为高效锰基氧还原电催化剂的设计提供了一种新策略,也为电化学能量转换与存储装置提供了一种理想的候选材料.
Overcoming the slow kinetics and solving the poor charge transport capacity are two critical issues that have to be taken into account in the actualisation of ORR electrocatalysts.In this study,Ag1.8Mn8O16/MWCNTs hybrid materials were successfully prepared using MWCNTs as well-conducting carriers by a green,economical and readily available synthetic method.The Ag1.8Mn8O16/MWCNTs exhibited excellent oxygen reduction electrocatalytic activity.The onset and half-wave potentials reached 1.00 V and 0.79 V,respectively.The Tafel slope exhibited a decrease to 131.5 mV·dec-1,while the kinetic current density reached a high of 8.8 mA cm-2@0.75 V.The enhanced activity was attributed to the synergistic effect between Ag1.8Mn8O16 and MWCNTs.This study provides a promising strategy for the design of efficient manganese-based oxygen reduction electrocatalysts,which provide an ideal candidate for electrochemical energy conversion and storage devices.

Ag1.8Mn8O16MWCNTsoxygen reduction reactionelectrocatalyst

贺明化、孟文兵、杨堡

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和田师范专科学校,新疆 和田 848000

Ag1.8Mn8O16 MWCNTs 氧还原 电催化剂

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(7)