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加热温度对气相色谱法测定非甲烷总烃的影响

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非甲烷总烃作为挥发性有机物总体排放情况表征的重要因素之一,监测其数据的准确性及可靠性具有重要意义.本实验在气相色谱法测定固定污染源废气非甲烷总烃的预处理过程中,对废气样品采用不同加热温度进行处理后检测其非甲烷总烃含量,研究加热温度对非甲烷总烃测定结果的影响.结果表明:当固定污染源废气中含有较多高沸点、水溶性组分时,进样前加热样品有助于样品的恢复,检测数据更具真实性和代表性,待测气体加热至160℃,可有助于提高本次实验样品的准确性和代表性.较短碳链(C2—C4)的烷烃和排放污染物浓度较低的固定污染源废气在不同温度下进行检测,对测定结果影响较小.
The Influence of Heating Temperature on the Determination of NMHC by GC
NMHC is one of the important factors to characterize the total emission of volatile organic compounds,so it is of great significance to monitor the accuracy and reliability of its data.In the pretreatment process of measuring the total non-methane hydrocarbons in waste gas from fixed pollution sources by GC,NMHC in waste gas samples were measured after being treated at different heating temperatures,and the influence of heating temperature on the determination results was studied.The results show that when the waste gas from stationary pollution sources contains more high boiling point and water-soluble components,heating the sample before injection is helpful to the recovery of the sample,and the test data is more authentic and representative.Heating the gas to be tested to 160℃can help to improve the accuracy and representativeness of the test sample.The alkane with shorter carbon chain(C2~C4)and the waste gas from fixed pollution source with lower pollutant concentration are detected at different temperatures,which has little influence on the determination results.

heating temperatureNMHCGCstationary source

胡柱均

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广东智环创新环境科技有限公司,广东 广州 510000

加热温度 非甲烷总烃 气相色谱法 固定污染源废气

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(7)