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汽车尾气排放PM2.5/PM10化学成分分析

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全球范围内,雾霾的形成及其对人类健康的影响已经成为环境研究的重点.其中,交通尾气排放的微小颗粒物(例如PM2.5 和PM10)是关键的研究领域.针对这一问题,实验选择了南京市作为案例研究地点,在一次严重空气污染事件中,对汽车尾气排放中可吸入颗粒物的化学成分展开分析.结果发现,汽油车排放的颗粒物中碳组分较少,且有机碳(OC)与元素碳(EC)的比值远高于柴油车.在水溶性离子方面,所有车型排放的颗粒物中,钠离子、硝酸根和硫酸根的含量占主导,这些差异主要与高温燃烧过程中氮氧化物(NOx)的排放和尾气中硫酸盐的形成有密切关系.在金属元素含量方面,还可以观察到汽油车的排放物中金属含量普遍高于柴油车,这一现象可能与车辆的质量相关.综上所述,机动车的尾气排放无疑是城市空气污染的重要因素之一;可以通过减少二次有机碳、降低金属部件的使用为策略,从而减少城市大气污染.
Chemical Composition Analysis of PM2.5/PM10 Emissions from Automobile Exhaust
The formation of haze and its impact on human health have become a focus of environmental research worldwide.Among them,the small particulate matter(such as PM2.5 and PM10)emitted from traffic exhaust is a key research area.In response to this issue,the experiment chose Nanjing as the case study location to analyze the chemical composition of inhalable particulate matter in automobile exhaust emissions during a severe air pollution incident.It was found that gasoline vehicles emitted fewer carbon components in particulate matter,and the ratio of organic carbon(OC)to elemental carbon(EC)was much higher than that of diesel vehicles.In terms of water-soluble ions,sodium ions,nitrate ions,and sulfate ions dominate the particulate matter emissions of all vehicle models.These differences are mainly related to the emission of nitrogen oxides(NOx)during high-temperature combustion and the formation of sulfates in exhaust gases.In terms of metal element content,it can also be observed that the metal content in the emissions of gasoline vehicles is generally higher than that of diesel vehicles,which may be related to the quality of the vehicles.In summary,the exhaust emissions of motor vehicles are undoubtedly one of the important factors contributing to urban air pollution.Reducing secondary organic carbon and decreasing the use of metal components can be strategies to reduce urban air pollution.

automobile exhaustchemical compositionatmospheric particulate matterenvironmental pollution

王勇

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甘肃省平凉生态环境监测中心,甘肃 平凉 744000

汽车尾气 化学成分 大气颗粒物 环境污染

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(7)