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不同还原剂处理电镀含铬废水的效果分析与比较

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化学沉淀法是处理电镀行业含铬废水的常用方法,通常采用还原剂加水解的方式,使铬最终以氢氧化铬的形式实现固液分离.研究了几种不同类型的还原剂在处理含铬废水的过程中表现出的效果和特性,并从处理效果、表观现象、药剂成本、产生渣量等方面展开对比分析.研究表明:在原水铬质量浓度为 500 mg/L的情况下,硫酸亚铁、亚硫酸氢钠和焦亚硫酸钠均能使六价铬处理至满足《电镀污染物排放标准》(GB 21900-2008)中六价铬的排放要求(<0.2 mg/L),但是从氢氧化钠消耗量、絮凝沉淀后的表观现象、产生渣量、总药剂成本等方面进行全方位对比后综合考虑,亚硫酸氢钠的消耗量和水解过程中所需的氢氧化钠量最少,因此总药剂成本最低,且产生渣量最少,出水表观无色澄清,是最适合的还原剂.
Effect Analysis and Comparison of Different Types of Reducing Agents on Treatment of Electroplating Wastewater Containing Chromium
Chemical precipitation is a common method to treat chromium-containing wastewater in electroplating industry,which usually adopts the way of reducing agent and hydrolysis to achieve solid-liquid separation of chromium in the form of chromium hydroxide.The effects and characteristics of several different types of reducing agents in the treatment of chromium-containing wastewater were studied,and the treatment effects,apparent phenomena,pharmaceutical costs,and slag production were compared and analyzed.The results show that ferrous sulfate,sodium bisulfite and sodium metabisulfite can all make hexavalent chromium treatment meet the emission requirements(<0.2 mg/L)of hexavalent chromium in the Discharge Standard of Electroplating Pollutants(GB21900-2008)when the concentration of chromium in raw water is 500 mg/L,but from the aspects of sodium hydroxide consumption,the apparent phenomenon after flocculation and precipitation,the amount of slag produced,the total cost of the agent after comprehensive consideration,the consumption of sodium bisulfite and the amount of sodium hydroxide required in the hydrolysis process are the least,so the total cost of the agent is the lowest,the amount of slag produced is the least,the effluent is apparently colorless and clear,and it is the most suitable reducing agent.

electroplatechromium-containing wastewaterreductanteffect analysiscost and amount of slag

易玉龙、刘果实、吴财松、高宝钗、谢品、林毅

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赛恩斯环保股份有限公司,湖南 长沙 410000

电镀 含铬废水 还原剂 效果分析 成本与渣量

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(7)