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高含CO2煤层气脱碳工艺选择及应用探讨

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煤层气气体组分以CH4 为主,另外含有少量CO2 与N2 等非烃气体.其中CH4 和CO2、N2 所占比例互为消长关系.N2 为惰性气体,其含量高低除了影响煤层气使用热值外无其他危害,而CO2 浓度过高明显降低煤层气的热值和燃烧效率,同时还会腐蚀地面集输管道和处理装置,缩短金属管道及设备的使用寿命,因此脱碳是高含CO2 煤层气高效利用的重要途径.本文介绍了三种适用于煤层气脱碳的成熟工艺,从装置一次性投资、甲烷回收率、运行成本等方面进行了综合对比.鉴于煤层气产量低,建议采用MDEA法高效处理高含CO2 煤层气,以获得较高的甲烷回收率,使煤层气商品率和经济效益达到最大化.
Discussion on the Selection and Application of Decarbonization Process for High CO2 Coalbed Methane
The main component of coalbed methane gas is CH4,with a small amount of non hydrocarbon gases such as CO2 and N2.The proportion of CH4,CO2,and N2 is in a reciprocal relationship.N2 is an inert gas,and its content not only affects the calorific value of coalbed methane,but also poses no other hazards.However,a high concentration of CO2 significantly reduces the calorific value and combustion efficiency of coalbed methane,and can also corrode surface gathering and processing pipelines and equipment,shortening the service life of metal pipelines and equipment.Therefore,decarbonization is an important way to efficiently utilize high CO2 coalbed methane.This article introduces three mature processes suitable for decarbonization of coalbed methane,and provides a comprehensive comparison in terms of one-time investment in equipment,methane recovery rate,and operating costs.Given the low production of coalbed methane,it is recommended to use the MDEA method to efficiently process high CO2 coalbed methane,in order to achieve a higher methane recovery rate and maximize the commercial and economic benefits of coalbed methane.

coalbed methanecarbon dioxidedecarbonization processMDEA methodPSA methodmembrane method

陈浦、赵勇、温丽娟、史永祥

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新疆亚新煤层气投资开发(集团)有限责任公司,新疆 乌鲁木齐 830010

煤层气 二氧化碳 脱碳工艺 MDEA法 PSA法 膜法

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(8)