首页|锌离子电池磷酸钠正极材料的合成与电化学性能研究

锌离子电池磷酸钠正极材料的合成与电化学性能研究

扫码查看
水系锌离子电池近年来在储能领域备受关注.相较于常用的有机系电池,水系电池采用绿色环保的水系电解液,具有更高的安全性和成本优势.在水系锌离子电池中,正极材料占据着至关重要的位置,其中,磷酸钒钠因其简单的合成方法、离子传导快、结构稳定等优点逐渐为人们所推崇.本文通过溶胶凝胶法制备了磷酸钒钠材料,制造了磷酸钒钠全电池,研究磷酸钒钠的电化学性能和储锌机制.结果表明,磷酸钒钠表现出优异的电化学性能,其放电过程为Na+和Zn2+共嵌过程,该研究为锌离子电池正极材料的优化提供了理论支撑.
Synthesis and Electrochemical Properties of Sodium Vanadium Phosphate Cathode Materials for Zinc Ion Batteries
In recent years,aqueous zinc ion batteries have attracted much attention in the field of energy storage.Compared with organic batteries,aqueous batteries use environmentally friendly aqueous electrolyte,which has higher safety and great potential for development.In aqueous zinc ion batteries,cathode materials,especially sodium vanadium phosphate,have become competitive cathode materials for zinc ion batteries due to its simple synthesis method,fast ionic conduction and other advantages.In this paper,sodium vanadium phosphate materials were prepared,and sodium vanadium phosphate cathode materials were loaded into button batteries,and a series of material performance characterization and electrochemical performance tests were conducted to investigate the zinc storage performance and zinc storage mechanism of sodium vanadium phosphate.The results show that the sodium vanadium phosphate exhibits better performance characteristics,and its discharge process is a co-embedded process of Na+and Zn2+,which provides theoretical support for the optimization of the cathode materials for zinc ion batteries.

aqueous zinc ion batteriescathode materialssodium vanadium phosphatesol-gel methodelectrochemical properties

智芳芳

展开 >

晋中职业技术学院,山西 晋中 030600

水系锌离子电池 正极材料 磷酸钒钠 溶胶凝胶法 电化学性能

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(9)