Analysis of Controllable Gradient Copolymers Synthesized by Chemical Semi-continuous Reactor and RAFT Technology
This article uses semi continuous feeding method and RAFT technology to synthesize controllable gradient copolymers.Through experimental design,a series of St/BA copolymers with precise controllable composition curves are synthesized,and the RAFT reagent selected is BDIB.The feed rate of the comonomer was calculated through a kinetic model based on the composition chain length curve of the target copolymer.The composition distribution,molecular weight,and molecular weight distribution of the obtained copolymer were consistent with the model predictions.
chemical industrysemi-continuous reactorRAFT technologycontrollable gradientcopolymerexperimental synthesis
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