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煤矸石对重金属污染土壤pH值和Pb有效态的影响

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煤矸石固态废物利用是解决土壤污染的化工手段之一,为此分析煤矸石添加下土壤理化性质发生的变化,并通过实验测试的手段分析煤矸石对重金属污染土壤pH值和Pb有效态的影响.研究结果表明:煤矸石钝化会提高土壤的碱性.添加量在1%~15%范围时,土壤将会达到更大pH值,由 6.53 增加到 6.64,煤矸石改良土壤pH和提高重金属的生物可利用性都具有较好效果.逐渐提高煤矸石添加量后,土壤内形成了更低可利用性元素浓度,并逐步趋于平衡状态,可使Pb的可利用性下降2.21%~16.31%.该研究有助于从化工角度提高对煤矸石化学性能的理解,为后续煤矸石的利用效率提高发挥一定作用.
Effect of Coal Gangue on pH Value and Pb Available State of Heavy Metal Contaminated Soil
The utilization of solid waste of coal gangue is one of the chemical methods to solve soil pollution.For this reason,the change of physical and chemical properties of soil under the addition of coal gangue is analyzed,and the influence of coal gangue on the pH value and Pb effective state of soil polluted by heavy metals is analyzed by means of experimental testing.The results show that the passivation of coal gangue can increase the alkalinity of soil.When the addition amount is increased in the range of 1%~15%,the soil pH value will reach a larger value,increasing from 6.53 to 6.64.Coal gangue has a good effect on improving soil pH and improving its bioavailability to heavy metals.Gradually increasing the amount of coal gangue,the soil formed a lower concentration of available elements,and gradually regional equilibrium state,can reduce the availability of Pb 2.21%~16.31%.This study is helpful to improve the understanding of the chemical properties of coal gangue from the perspective of chemical engineering,and plays a certain role in improving the utilization efficiency of coal gangue in the future.

coal ganguesoil remediationheavy metalspassivationmorphological transformation

娄明坤

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中煤平朔发展集团有限公司生活服务公司,山西 朔州 038500

煤矸石 土壤修复 重金属 钝化 形态转化

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(9)