首页|基于ZIF-67多孔碳/MnO2复合材料的制备及其电化学性能研究

基于ZIF-67多孔碳/MnO2复合材料的制备及其电化学性能研究

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MOF材料由于其超高比表面积、多样的结构等特点成为高比电容储能材料的研究热点.本文采用快速氧化还原法,以ZIF-67 为碳源制备C/MnO2 复合材料.通过SEM分析可知复合材料仍然保持ZIF-67 的多面体结构,电化学性能分析可知,在KOH电解液中,电流密度为 0.5 A/g下比电容为 156.5 F/g,10A/g下比电容为 72.5 F/g,比电容保持率为54%,具有良好的倍率特性,是一种优良的超级电容器电极材料.
Preparation and Electrochemical Properties of ZIF-67 Porous Carbon/MnO2 Composite Material
MOF materials have become a research hotspot in high specific capacitance energy storage materials due to their ultra-high surface area and diverse structures.This article uses rapid oxidation-reduction method to prepare C/MnO2 composite materials with ZIF-67 as the carbon source.According to SEM analysis,the composite material still maintains the polyhedral structure of ZIF-67.Electrochemical performance analysis shows that in KOH electrolyte,the specific capacitance is 156.5 F/g at a current density of 0.5 A/g and 72.5 F/g at 10 A/g,with a specific capacitance retention rate of 54%.It has good rate characteristics and is an excellent electrode material for supercapacitors.

oxidation-reduction methodMOF materialssupercapacitorselectrochemical performance

解玲丽、王飞、赵赟、陈红英

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山西工程职业学院,山西 太原 030009

氧化还原法 MOF材料 超级电容器 电化学性能

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(10)