山西化工2024,Vol.44Issue(10) :23-26.DOI:10.16525/j.cnki.cn14-1109/tq.2024.10.008

基于ZIF-67多孔碳/MnO2复合材料的制备及其电化学性能研究

Preparation and Electrochemical Properties of ZIF-67 Porous Carbon/MnO2 Composite Material

解玲丽 王飞 赵赟 陈红英
山西化工2024,Vol.44Issue(10) :23-26.DOI:10.16525/j.cnki.cn14-1109/tq.2024.10.008

基于ZIF-67多孔碳/MnO2复合材料的制备及其电化学性能研究

Preparation and Electrochemical Properties of ZIF-67 Porous Carbon/MnO2 Composite Material

解玲丽 1王飞 1赵赟 1陈红英1
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作者信息

  • 1. 山西工程职业学院,山西 太原 030009
  • 折叠

摘要

MOF材料由于其超高比表面积、多样的结构等特点成为高比电容储能材料的研究热点.本文采用快速氧化还原法,以ZIF-67 为碳源制备C/MnO2 复合材料.通过SEM分析可知复合材料仍然保持ZIF-67 的多面体结构,电化学性能分析可知,在KOH电解液中,电流密度为 0.5 A/g下比电容为 156.5 F/g,10A/g下比电容为 72.5 F/g,比电容保持率为54%,具有良好的倍率特性,是一种优良的超级电容器电极材料.

Abstract

MOF materials have become a research hotspot in high specific capacitance energy storage materials due to their ultra-high surface area and diverse structures.This article uses rapid oxidation-reduction method to prepare C/MnO2 composite materials with ZIF-67 as the carbon source.According to SEM analysis,the composite material still maintains the polyhedral structure of ZIF-67.Electrochemical performance analysis shows that in KOH electrolyte,the specific capacitance is 156.5 F/g at a current density of 0.5 A/g and 72.5 F/g at 10 A/g,with a specific capacitance retention rate of 54%.It has good rate characteristics and is an excellent electrode material for supercapacitors.

关键词

氧化还原法/MOF材料/超级电容器/电化学性能

Key words

oxidation-reduction method/MOF materials/supercapacitors/electrochemical performance

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出版年

2024
山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
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