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电池负极材料上电纺丝沉积碳纳米纤维结构和性能分析

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纤维结构具有良好的韧性和导电性能,在电池负极材料上得到广泛应用.为此通过电纺丝沉积的方式制备碳纳米纤维材料,并通过实验测试的手段开展微观组织和光谱性能分析.研究结果表明:适当增加镍片与电纺丝距离有助于碳纳米纤维形成,经过3 min烧结后获得有限数量碳纳米纤维,大部分以颗粒状态存在.纤维内部存在C、Ni、O以及微量的Li元素,成功生产出富含碳的纳米纤维.N2 吸附与解吸曲线表现为典型的Ⅱ类等温吸附特点,孔径集中分布在9.2 nm附近.碳纳米纤维拉曼光谱形成了明显的D带与G带,D带峰值出现在约1 327 cm-1 处,G带在 1 587 cm-1 位置显现出强度.该研究有助于提高电池对碳纳米纤维的认识,为后续的性能进一步优化奠定一定的理论基础.
Structure and Properties Analysis of Carbon Nanofibers Deposited by Electrospinning on Battery Cathode Materials
Fiber structure has good toughness and conductive properties,and has been widely used in battery anode materials.Carbon nanofibers were prepared by electrospinning deposition,and their microstructure and spectral properties were analyzed by means of experimental testing.The results show that increasing the distance between nickel sheet and electrospinning is beneficial to the formation of carbon nanofibers.After 3 min sintering,a limited number of carbon nanofibers are obtained,most of which exist in granular state.The presence of C,Ni,O and trace amounts of Li elements in the fibers successfully produced carbon-rich nanofibers.N2 adsorption and desorption curves are typical of Class Ⅱ isothermal adsorption,and the pore size is concentrated around 9.2 nm.The Raman spectra of carbon nanofibers formed obvious D and G bands,the peak of D band appeared at about 1 327 cm-1,and the intensity of G band appeared at 1 587 cm-1.This study helps to improve the understanding of carbon nanofibers in batteries,and lays a theoretical foundation for further optimization of subsequent performance.

ethanol electrospinningcarbon nanofiberssurface modificationperformance analysis

郭静斐

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宁德时代新能源科技股份有限公司,福建 宁德 352100

乙醇电纺丝法 碳纳米纤维 表面改性 性能分析

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(10)