山西化工2024,Vol.44Issue(10) :116-118.DOI:10.16525/j.cnki.cn14-1109/tq.2024.10.039

基于MgAlRu-500R光热催化合成氨速率分析

Analysis of Ammonia Synthesis Rate Based on MgAlRu-500R Photothermal Catalysis

孙伟
山西化工2024,Vol.44Issue(10) :116-118.DOI:10.16525/j.cnki.cn14-1109/tq.2024.10.039

基于MgAlRu-500R光热催化合成氨速率分析

Analysis of Ammonia Synthesis Rate Based on MgAlRu-500R Photothermal Catalysis

孙伟1
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作者信息

  • 1. 山西兴新安全生产技术服务有限公司,山西 太原 030008
  • 折叠

摘要

为解决传统合成氨催化剂制备复杂、反应速率低、资源浪费等问题,提出MgAlRu-500R光热催化合成氨生产工艺.根据实验要求制备催化剂,从吸光度和宽光谱吸收性能两方面进行MgAlRu-500R吸光度测试,分析常压条件下的光热催化合成氨性能,评估催化剂应用效果.结果表明,常压条件下,MgAlRu-500R催化剂可发生合成氨反应,温度影响产氨速率,380℃时达到 3.0 mmol/(g·h);温度一致时,催化剂在光热催化时的活性较纯热催化大幅提高;光的引入加速解离氮气分子,提高产氨速率.MgAlRu-500R光热催化合成氨工艺应用效果良好,对氨合成产业发展起到推动作用.

Abstract

To solve the problems of complex preparation,low reaction rate,and resource waste in traditional ammonia synthesis catalysts,the MgAlRu-500R photothermal catalytic ammonia production process is proposed.Prepare the catalyst according to the experimental requirements,conduct MgAlRu-500R absorbance testing from both absorbance and broad-spectrum absorption performance,analyze the performance of photothermal catalytic synthesis of ammonia under atmospheric pressure conditions,and evaluate the application effect of the catalyst.The results showed that under normal pressure,MgAlRu-500R catalyst can undergo ammonia synthesis reaction,and temperature affects the ammonia production rate,reaching 3.0 mmol/(g·h)at 380℃.When the temperature is consistent,the activity of the catalyst in photothermal catalysis is significantly improved compared to pure thermal catalysis.The introduction of light accelerates the dissociation of nitrogen molecules and increases the rate of ammonia production.The application effect of MgAlRu-500R photothermal catalytic synthesis of ammonia is good,which plays a promoting role in the development of ammonia synthesis industry.

关键词

光热催化剂/合成氨/吸收光谱测试/速率

Key words

photothermal catalyst/synthetic ammonia/absorption spectroscopy testing/rate

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出版年

2024
山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
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