首页|SNAR除酸脱硝技术在浙石化蜡油催化裂化装置的应用

SNAR除酸脱硝技术在浙石化蜡油催化裂化装置的应用

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浙江石油化工有限公司 300 万t/a蜡油催化裂化装置外排烟气因硫酸气溶胶含量较高,导致颗粒物浓度超标,联合青岛惠城环保科技集团股份有限公司进行一种SNAR除酸脱硝工艺技术的工业应用试验.利用气力输送将固体粉末状还原剂喷入催化装置的烟道,固体还原剂分解为气态还原性物质,与SO3 和NOx发生反应.工业应用结果表明,可大幅度降低SO3 浓度,SO3 脱除率为41.1%~57.7%,从而降低外排烟气中的硫酸盐气溶胶颗粒物的含量,保证颗粒物达标排放,并显著改善了工业烟气拖尾情况.同时NOx脱除率可达 50%~70%.该工业应用研究表明,SNAR除酸脱硝工艺具有很高的除酸脱硝效果,同时未对生产线设备产生腐蚀等不良影响,为催化裂化设备安全运行增加了经济收益和环保效益,具有一定应用前景.
Application of SNAR Acid and Nitrogen Removal Technology in the Catalytic Cracking Unit of Zhejiang Petrochemical's Wax Oil
Due to the high content of sulfuric acid aerosols in the exhaust gas of the 3 million t/a wax oil catalytic cracking unit of Zhejiang Petroleum&Chemical Co.,Ltd.,the particulate matter concentration exceeded the standard.In conjunction with Qingdao Huicheng Environmental Protection Technology Group Co.,Ltd.,an industrial application test of SNAR acid removal and denitrification process technology was conducted.Using pneumatic conveying to spray solid powdered reducing agent into the flue of the catalytic device,the solid reducing agent decomposes into gaseous reducing substances,which react with SO3 and NOx.The industrial application results show that the concentration of SO3 can be significantly reduced,with a SO3 removal rate of 41.1%~57.7%,thereby reducing the content of sulfate aerosol particles in the exhaust gas,ensuring that the particles meet the emission standards,and significantly improving the tailing situation of industrial flue gas.At the same time,the NOx removal rate can reach 50%~70%.The industrial application research shows that the SNAR acid and denitrification process has a high acid and denitrification effect,and does not have adverse effects such as corrosion on production line equipment,which increases economic and environmental benefits for the safe operation of catalytic cracking equipment and has certain application prospects.

catalytic crackingsulfuric acid aerosolblue smoke plumeSO3nitrogen oxide

王金生、李超、康浩、刘建、郑小辉、张欣、王国刚

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浙江石油化工有限公司,浙江 舟山 316200

青岛惠城环保科技集团股份有限公司,山东 青岛 266500

催化裂化 硫酸气溶胶 蓝色烟羽 SO3 氮氧化物

2024

山西化工
山西省煤化工发展促进中心 山西省化工学会

山西化工

影响因子:0.293
ISSN:1004-7050
年,卷(期):2024.44(10)