首页|复配表面活性剂对岩尘润湿性的影响

复配表面活性剂对岩尘润湿性的影响

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以余吾矿区岩尘作为研究对象,通过分子模拟法探究复配表面活性剂AEO-7/DTAB、AEO-7/SDS和AEO-7/SDBS对岩尘表面润湿性的影响以及在各岩石体系的聚集行为以及润湿机理.研究发现,岩尘在阴离子/非离子复配体系中的润湿速度与其他溶液相比表现出显著的协同效应;表面活性剂分子在复配体系中通过形成胶束聚集体,降低溶液的临界胶束浓度.通过计算模拟体系的相互作用能,液相与各岩石之间相互作用能大小顺序遵循高岭石>白云母>石英的规律.同时,对比单一表面活性剂对岩石润湿性的影响,可以看出复配溶液在提高高岭石和石英石的润湿性能上更有优势,而对于改变白云母体系的润湿效果较难.
Influence of composite surfactant on the wettability of rock dust
This article takes rock dust from Yuwu mining area as the research object and explores the influence of composite surfactant AEO-7/DTAB,AEO-7/SDS,and AEO-7/SDBS on the surface wettability of rock dust,as well as their aggrega-tion behavior and wetting mechanism in various rock systems through molecular simulation.The conclusion is that the wet-ting rate of rock dust in the anionic/non ionic composite system exhibits a significant synergistic effect compared to other so-lutions.Surfactant molecules form micelle aggregates in the composite system,reducing the critical micelle concentration of the solution.By calculating the interaction energy of the simulation system,the order of the interaction energy between the liquid phase and the rocks follows the law of kaolinite>muscovite>quartz.At the same time,by comparing the influence of single surfactant on rock wettability,the compound solution has more advantages in improving the wettability of kaolinite and quartz,but it is difficult to change the wettability of muscovite system.

compound surfactantrock dustmolecular simulationinteraction energywetting effect

王志坚

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潞安化工集团余吾煤业有限公司,山西长治 046100

复配表面活性剂 岩尘 分子模拟 相互作用能 润湿效果

辽宁省教育厅青年项目

LJKQZ20222334

2024

陕西煤炭
陕西省煤炭工业协会 神华神东煤炭集团有限责任公司 陕西煤业化工集团有限责任公司

陕西煤炭

影响因子:0.204
ISSN:1671-749X
年,卷(期):2024.43(4)
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