首页|GO改性C/C复合材料的制备及其电磁屏蔽性能

GO改性C/C复合材料的制备及其电磁屏蔽性能

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为了获得一种制备简单、成本低廉的电磁屏蔽材料,通过喷涂法在2D碳纤维(carbon fiber,CF)预制体上负载氧化石墨烯(graphene oxide,GO),并以硼酚醛树脂(boron-phenolic resin,BPF)作为前驱体,石墨烯负载碳纤维(GO/CF)作为预制体,通过热压成型和碳化工艺制备得到氧化石墨烯改性碳/碳复合材料(GO/C/C).采用X射线衍射(X-ray diffraction,XRD)、扫描电子显微镜(scanning electron microscope,SEM)、拉曼光谱(Raman spec-trum)、密度仪(densitometer)和矢量网络分析仪(vector network analyzer)对复合材料进行表征.结果表明,当GO的负载量为0.1%、0.3%时,GO/CF预制体的表面形貌最好;负载量为0.3%时,复合材料具有最高的孔隙率和最低的电阻率;负载量为0.1%时,复合材料在X波段的总电磁屏蔽效能最高,达到了 43.84 dB,相比于空白样品提高了 28.3%,已满足基本的商用需求.
Preparation and electromagnetic interference properties of GO modified C/C composites
In order to obtain a simple and low-cost electromagnetic shielding material,the 2D carbon fiber(CF)precast was loaded with graphene oxide(GO)by spraying method,and the boron-phenolic resin(BPF)was used as the precursor,and the graphene supported carbon fiber(GO/CF)was used as the precast.GO modified carbon/carbon composites(GO/C/C)were prepared by hot press molding method and carbonization process.X-ray Diffraction(XRD),scanning electron microscope(SEM),Raman spectrum,densitometer and vector network analyzer were used to characterize the composites.The results show that the surface morphology of GO/CF preform is the best when the load of GO is 0.1%and 0.3%.When GO content is 0.3%,the composites have the highest porosity and the lowest resistivity.When the load of GO is 0.1%,the total electromagnetic shielding effi-ciency of the composite in the X-band is the highest,reaching 43.84 dB,which is 28.3%higher than that of the blank sample,and has met the basic commercial requirements.

carbon/carbon compositesgraphene oxideelectromagnetic shieldingre-sistivityporosity

宁立新、陈泽超、洪建婷、王旭、彭雨晴、张方舟、吴艺峰、刘立起

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上海大学材料科学与工程学院,上海 200444

上海大学绍兴研究院,浙江绍兴 312074

上海佳和化学有限公司,上海 201415

碳/碳复合材料 氧化石墨烯 电磁屏蔽 电阻率 孔隙率

云南省重大科技专项资助项目

202002AB080001-2

2024

上海大学学报(自然科学版)
上海大学

上海大学学报(自然科学版)

CSTPCD北大核心
影响因子:0.579
ISSN:1007-2861
年,卷(期):2024.30(4)