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丝胶蛋白改性聚丙烯腈纤维性能测试分析

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用丝胶蛋白对腈纶进行改性,以获得力学性能良好、吸湿性改善的纤维.通过改变拉伸倍数,研究其对纤维力学性能的影响.通过改变干燥致密化工艺,研究纤维内部结晶度的变化及其对力学性能的影响.结果表明:总拉伸倍数增大,纤维取向度增加,力学性能随之提高;两道拉伸的总倍数为6.5倍时,得到的纤维断裂强度最佳,为3.87 cN/dtex;纤维干燥致密化温度为120℃,致密化时间为110 s,所得纤维的性能最佳;致密化温度过高,纤维的结晶取向下降;在最佳致密化条件下,纤维的断裂强度为3.8 cN/dtex;丝胶蛋白改性聚丙烯腈纤维的回潮率为6.9%,较常规腈纶提高了 3.5 倍.
Performance testing and analysis of silk glue protein modified polyacrylonitrile fiber
Acrylic is modified with silk gum protein to obtain fibers with good mechanical properties and improved moisture absorption.The effect on the mechanical properties of the fibers is investigated by varying the tensile multiplier.By changing the drying densification process,the change of internal crystallinity of the fiber and the effect of this change on the mechanical properties are investigated.The results show that as the total stretching ratio increases,the fiber orientation degree increases,and the mechanical properties also improve;When the total multiple of two stretching cycles is 6.5 times,the fiber fracture strength obtained is the best,which is 3.87 cN/dtex;The fiber performance is optimal when the drying and densification temperature is 120 ℃ and the densification time is 110 s;If the densification temperature is too high,the crystal orientation of the fibers decreases;Under the optimal densification conditions,the fracture strength of the fiber is 3.8 cN/dtex;The moisture regain of silk fibroin modified polyacrylonitrile fibers is 6.9%,which is 3.5 times higher than that of conventional acrylic fibers.

silk glue proteinpolyacrylonitrile fibermodificationmoisture regainmechanical property

曹丽、王玢岩、程隆棣、张瑞云、吴建华

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东华大学纺织学院,上海 201620

吴江鼎盛丝绸有限公司,江苏苏州 215228

丝胶蛋白 聚丙烯腈纤维 改性 回潮率 力学性能

2024

上海纺织科技
上海市纺织科学研究院

上海纺织科技

CSTPCD
影响因子:0.476
ISSN:1001-2044
年,卷(期):2024.52(2)
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