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紫外光接枝对茜草染料染色性能的影响

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采用紫外线光接枝技术,将偶联剂γ-甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)和纳米氧化锌(ZnO)接枝到棉织物表面,并以纳米氧化锌作为媒染剂,可以使茜草天然染料在室温、不加盐的条件下上染棉织物.探讨了偶联剂KH-570、光敏引发剂染料质量分数和紫外线照射能量等因素对棉织物染色性能的影响.采用SEM、FTIR、EDS和XPS对染色前后棉织物的表面形貌和结构进行了表征.结果表明,偶联剂KH-570质量分数为3%、光敏引发剂质量分数为3%、紫外线照射能量为15 J/cm2、染料质量分数为25%时,棉织物染色深度K/S值可达8.32,耐皂洗色牢度为4级,耐干、湿摩擦色牢度分别为5级、4~5级.
Effect of UV-induced photografting on the dyeability of Madder dye
The coupling agent γ-methylacryloxy propyl trimethoxysilane(KH-570)and nano-zinc oxide(ZnO)are grafted onto the surface of cotton fabric by UV photografting technology.Nano-zinc oxide is used as a mordant to dye cotton fabric with natural madder dyes at room temperature without salt addition.The influences of coupling agent concentration,photo sensitive initiator concentration,UV irradiation energy and dye concentration on the dyeability of cotton fabrics are discussed.The surface morphology and structure of cotton fabric before and after dyeing are characterized by FTIR,SEM,EDS and XPS.The results show that when the mass fraction of coupling agent KH-570 is 3%,the mass fraction of photosensitive initiator is 3%,the UV irradiation energy is 15 J/cm2,and dye concentration is 25%,the dyeing depth K/S value of cotton fabric could reach 8.32,the color fastness to soaping is level 4,and the color fastness to dry and wet rubbing is level 5 and 4~5,respectively.

madder dyescotton fabricUV irradiationphotograftingdyeability

林志富、董媛媛、吕姣、杨依琳

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大连工业大学纺织与材料工程学院,辽宁大连 116034

茜草染料 棉织物 紫外线照射 光接枝 染色性能

辽宁省自然科学基金计划指导计划项目

2019-ZD-0290

2024

上海纺织科技
上海市纺织科学研究院

上海纺织科技

CSTPCD
影响因子:0.476
ISSN:1001-2044
年,卷(期):2024.52(6)