上海纺织科技2024,Vol.52Issue(9) :58-62.

基于湿法静电纺纱技术构建PI/rGO复合纱线及其性能

Preparation of PI/rGO composite yarn based on wet electrospinning technology and its performance

师晓含 周玉嫚 齐庆欢 张庆 王清清 吴以婧 王欣爽
上海纺织科技2024,Vol.52Issue(9) :58-62.

基于湿法静电纺纱技术构建PI/rGO复合纱线及其性能

Preparation of PI/rGO composite yarn based on wet electrospinning technology and its performance

师晓含 1周玉嫚 1齐庆欢 1张庆 1王清清 1吴以婧 1王欣爽1
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作者信息

  • 1. 中原工学院纺织服装产业研究院,河南郑州 450007
  • 折叠

摘要

为制备性能优异的石墨烯基纱线,选择聚酰胺酸(PAA)作为纺丝聚合物,氧化石墨烯(GO)水分散液作为凝固浴,利用湿法静电纺纱技术构建PAA/GO复合纱线,进一步通过高温作用获得聚酰亚胺/还原氧化石墨烯(PI/rGO)复合纱线.表征了PI/rGO复合纱线的形貌和化学结构,研究了PI/rGO复合纱线的力学性能和导电性能,并对其电性能的实际应用性能进行测试.结果表明:PI/rGO复合纱线形貌优异,且拥有优异的力学性能和导电性能;当GO质量浓度达到10 mg/mL时,PI/rGO复合纱线的断裂伸长率达到16.5%,断裂强度达到21.06 MPa,电阻达到210 kΩ,能够单独使用或编织成织物作为导线点亮LED灯泡;同时,PI/rGO复合纱线也表现出理想的双电层电容特性和电化学性能.

Abstract

In order to prepare high-performance graphene-based yams,polyamide acid/graphene oxide(PAA/GO)composite yarn is first constructed by wet electrospinning technology and then subjected to high-temperature treatment to transform into polyimide/reduced graphene oxide(PI/rGO)composite yarn,with polyamide acid(PAA)as spinning polymer and graphene oxide(GO)aqueous dispersion as coagulation bath.The morphology and chemical structure of PI/rGO composite yarns are characterized.The mechanical and electrical properties of PI/rGO composite yarns are researched,and the electrical properties are also tested for practical application.The results show that the PI/rGO composite yam has excellent morphology,outstanding mechanical and prominent electrical properties.The elongation at break,the breaking strength,and the resistance of PI/rGO composite yarn respectively reach to 16.5%,21.06 MPa,and 210 kΩ.When the GO concentration is 10 mg/mL,which could be used alone or woven into fabrics as wires to light LED bulbs.Furthermore,PI/rGO composite yarns also exhibit ideal double layer capacitance characteristics and electrochemical properties.

关键词

湿法静电纺纱/石墨烯/聚酰亚胺/复合纱线/电学性能

Key words

wet electrospinning/graphene/polyimide/composite yam/electrical property

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基金项目

中原工学院研究生科研创新计划项目(YKY2023ZK55)

大学生创新创业训练计划项目(202310465023)

出版年

2024
上海纺织科技
上海市纺织科学研究院

上海纺织科技

CSTPCD
影响因子:0.476
ISSN:1001-2044
参考文献量8
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