上海涂料2024,Vol.62Issue(4) :1-9.

聚氯乙烯-水性聚氨酯水乳胶的合成与性能研究

Preparation and Performance of Polyvinyl Chloride-Waterborne Polyurethane Latex

张悦 吴宇 董晓宇 王淑芬 唐家鹏 饶祥 丁运生
上海涂料2024,Vol.62Issue(4) :1-9.

聚氯乙烯-水性聚氨酯水乳胶的合成与性能研究

Preparation and Performance of Polyvinyl Chloride-Waterborne Polyurethane Latex

张悦 1吴宇 1董晓宇 2王淑芬 3唐家鹏 3饶祥 2丁运生2
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作者信息

  • 1. 合肥工业大学材料科学与工程学院,安徽合肥 230009
  • 2. 合肥工业大学化学与化工学院先进功能材料与器件安徽省重点实验室,安徽合肥 230009
  • 3. 合肥大学能源材料与化学工程学院,安徽合肥 230000;安徽省绿色涂料高性能助剂工程研究中心,安徽合肥 230000
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摘要

发展低挥发性有机物(VOCs)含量的水性涂料是降低污染、助力实现"双碳"目标的有效途径.本研究合成了可聚合水性聚氨酯(WPU),以其作为共聚单体与可聚合乳化剂,以聚氯乙烯(PVC)水乳胶为种子,同时引入氮丙啶(H-100)交联剂,通过半连续种子乳液聚合法制备了聚氯乙烯-水性聚氨酯(PVC-WPU)水乳胶.将该水乳胶用于金属防腐蚀涂层,通过接触角、吸水率、附着力、电化学测试分析等方法考察了涂层的防腐蚀性能.结果表明,在3.5%的NaCl溶液中浸泡5 d后,交联聚氯乙烯-水性聚氨酯(C-PVC-WPU)涂层的低频阻抗值(|Z|f=0.01 Hz)约为107 Ω·cm2,腐蚀抑制效率为99.98%.

Abstract

Developing low volatile organic compound(VOCs)content water-based coatings is an effective approach to reducing pollution and aiding in the achievement of dual carbon goals.In this paper,a polymerizable waterborne polyurethane(WPU)was synthesized,which was used as a comonomer and a polymerizable emulsifier.With polyvinyl chloride(PVC)latex as the seed and aziridine(H-100)as the crosslinking agent,PVC-WPU latex was prepared by semi-continuous seed emulsion polymerization.The latex was applied to metal anti-corrosion coatings,and the anti-corrosion performance of the coatings was investigated through methods such as contact angle,water absorption,adhesion,and electrochemical testing analysis.The results showed that the low-frequency impedance value(|Z|f=0.01 Hz)of C-PVC-WPU(7%DMPA)coating is approximately 107 Ω·cm2 and the corrosion inhibition efficiency is 99.98%after soaking in 3.5%NaCl solution for 5 days.

关键词

聚氯乙烯/水性聚氨酯/防腐蚀/水性涂料/水乳胶

Key words

polyvinyl chloride/polyurethane/corrosion resistance/waterborne coating/latex

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基金项目

安徽省自然科学基金(2208085QE137)

安徽省重大科技专项-成果工程化研发项目(202203C08020009)

出版年

2024
上海涂料
上海涂料有限公司 上海市涂料研究所

上海涂料

影响因子:0.412
ISSN:1009-1696
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