应用技术学报2024,Vol.24Issue(1) :48-54.DOI:10.3969/j.issn.2096-3424.2024.01.004

电芬顿法处理土壤淋洗废水研究

Study on the treatment of soil washing waste agent by the electro-Fenton method

胡晓钧 张宏波 何卫警 秦娇龙 曹森武
应用技术学报2024,Vol.24Issue(1) :48-54.DOI:10.3969/j.issn.2096-3424.2024.01.004

电芬顿法处理土壤淋洗废水研究

Study on the treatment of soil washing waste agent by the electro-Fenton method

胡晓钧 1张宏波 1何卫警 2秦娇龙 1曹森武1
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作者信息

  • 1. 上海应用技术大学化学与环境工程学院,上海 201418
  • 2. 上海澄域环保工程有限公司,上海 201499
  • 折叠

摘要

土壤淋洗技术以其修复周期短,修复效果显著而被广泛应用于重金属污染土壤的修复.但淋洗过程中会产生大量的淋洗废液,这些淋洗废液中往往含有难降解的废弃淋洗剂、土壤腐殖质以及稳定性高的络合态重金属,难以采用传统的絮凝沉淀法直接处理达标.以亚氨基二琥珀酸(IDS)为淋洗剂处理工业Pb污染土壤后的淋洗废液为研究对象,以还原氧化石墨烯@石墨毡(RGO@GF)电极为阴极,利用电芬顿技术处理含IDS和Pb的淋洗废液,实验结果表明:外加电压 2.5 V,体系初始pH=3.0,反应 8h,氧气通量 100 mL/min时,对淋洗废液中的TOC去除率可达 56.29%,Pb去除率可达98.91%,明显高于同等条件下普通芬顿技术的处理效果.

Abstract

Soil washing technology has been widely used for the remediation of heavy metal contaminated soil due to its short remediation cycle and significant remediation effect.However,during the washing process,a large amount of soil washing waste liquid is generated,which often contains refractory waste leaching agents,soil humus,and highly stable complex heavy metals,making it difficult to be directly treated to meet the standards using conventional flocculation precipitation methods.In this study,the washing waste agent from actual industrial contaminated soil containing Pb was taken as the research object,and a new type of cathode material-RGO@GF(graphene oxide loaded on graphite felt)-was prepared.Electro-Fenton technology was used to treat the washing wastewater containing IDS and Pb.The experimental results showed that under the conditions of an applied voltage of 2.5 V,initial pH of 3.0,electrolysis time of 8 hours,and oxygen flow rate of 100 mL/min,the removal rate of TOC in the leachate reached 56.29%and the removal rate of Pb in the leachate reached 98.91%,which was higher than that of conventional Fenton technology under the same conditions.

关键词

土壤淋洗/电芬顿氧化技术/重金属/H2O2/氧化石墨烯

Key words

soil washing/electro-Fenton oxidation technology/heavy metals/H2O2/graphene oxide

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基金项目

上海市自然科学基金(23ZR1462300)

出版年

2024
应用技术学报
上海应用技术学院

应用技术学报

影响因子:0.195
ISSN:2096-3424
参考文献量20
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