首页|维生素E黏胶/石墨烯锦纶/蚕丝复合功能交织物的制备与研究

维生素E黏胶/石墨烯锦纶/蚕丝复合功能交织物的制备与研究

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高附加值、多功能纺织品成为纺织研究界探索的重要领域.本文通过将蚕丝、维生素E黏胶和石墨烯锦纶进行复合,设计织造了15 种织物,对其进行抗氧化性、远红外性能、抗紫外性能与抗静电性能的测试研究.采用响应面分析技术(RSM)研究了投纬比例和组织结构对功能性表达的影响关系,结合模糊多准测决策法(F-MCDM)对最佳工艺参数进行了评估.结果表明:两种纬纱的投纬比和织物组织对织物的功能性表达都有不同程度的影响,且影响是交互的复杂作用.当纬纱中维生素E黏胶和石墨烯锦纶的投纬比为1︰1、织物组织为八枚缎纹时,织物试样的四种功能性表达最好.
Preparation and study of vitamin E viscose/graphene nylon/silk composite functional fabrics
Mulberry silk is known as the"queen of natural fibers".It is one of the best choices for high-grade textiles.In recent years,the development of functional silk products has no longer focused on the research and development of a single function,but towards the direction of multi-functional integration.Vitamin E is one of the most common active ingredients in skin care products and has a strong antioxidant effect.Vitamin E is coated with microcapsules and added to the spinning solution,and the yarn with vitamin E formed by wet spinning has skin-care function.Graphene is a popular new textile raw material,with excellent mechanical properties,electrical conductivity,far infrared radiation properties,and solar ultraviolet radiation protective properties.To explore the possibility of applying these two functional materials to the preparation of multifunctional textiles,this article aims to explore the effects of the filling ratio of two kinds of functional yarns as well as fabric structure,and to quantitatively and systematically analyze the samples with the best comprehensive performance through mathematical methods.In this study,vitamin E viscose and graphene nylon were selected as weft yarn,and mulberry silk was selected as warp yarn.Antioxidant properties,far infrared radiation properties,solar ultraviolet radiation protective properties and electrostatic propensities were taken as functional objectives,and the filling ratio of the two weft yarns and fabric structure were taken as variables.The DPPH elimination rate,far infrared emissivity,far infrared radiation temperature rise,UPF,T(UVA)AV and HDT were used as measurement indexes for data analysis.Response surface methodology(RSM)was used to establish the model relationship between variables and the expression of functional performance,and analyze the effects of variables.Fuzzy multi-criteria decision method(F-MCDM)was used to comprehensively calculate and evaluate the samples,and the fabric sample with the best comprehensive performance was selected.The results show that the filling ratio of vitamin E viscos and graphene nylon and the fabric structure have effects on the antioxidant properties of the samples,and the influence of the three is pairwisely interactional.With the increase of the content of vitamin E viscose,the antioxidant properties of the fabrics are enhanced.The antioxidant performance in honeycomb weave is the best.With the increase of the content of graphene nylon,the far infrared emissivity and far infrared radiation temperature rise of the fabric are significantly enhanced,and the far infrared performance of honeycomb weave is the best.With the increase of the content of graphene nylon,solar ultraviolet radiation protective properties of the fabrics are generally enhanced.The anti-ultraviolet performance of double damask is the best,and that of the honeycomb weave is the worst.While the filling ratio of two kinds of weft yarns and fabric structure have pairwise interaction effects on UPF values,there is a triple interaction effect on T(UVA)AV.The electrostatic propensities of the samples are only related to the content of vitamin E viscose and graphene nylon in the weft yarns.When the filling yarn contains vitamin E viscos,the electrostatic propensity is significantly improved,but when the vitamin E viscose is reduced to a certain extent,the electrostatic propensities of the sample do not fluctuate and are still excellent.It is found through F-MCDM that when the filling ratio of vitamin E viscose yarn and graphene nylon is 1︰1 and the fabric is double damask,the comprehensive functional performance of the fabric is the best.When the filling ratio is 3︰1 or 1︰3 and the fabric is double damask,the comprehensive functional performance of the fabric is satisfactory.The result has certain reference significance for functional textile production enterprises.

silkvitamin E viscosegraphene polyamidecomposite functioninterwoven fabricresponse surface methodologyfuzzy multi-criteria decision method

李诗雅、张金珍、金肖克、丁圆圆、雷斌、祝成炎、张红霞

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浙江理工大学先进纺织材料与制备技术教育部重点实验室,杭州 310018

浙江理工大学浙江省纤维材料和加工技术研究重点实验室,杭州 310018

达利丝绸(浙江)有限公司,浙江 绍兴 312500

蚕丝 维生素E黏胶 石墨烯锦纶 复合功能 交织物 响应面分析技术 模糊多准测决策法

中央外经贸发展专项资金(茧丝绸)项目

浙财建202396号

2024

丝绸
浙江理工大学 中国丝绸协会 中国纺织信息中心

丝绸

CSTPCD北大核心
影响因子:0.567
ISSN:1001-7003
年,卷(期):2024.61(11)