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碱金属氯化物对铁矿粉高温烧结性能的影响

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针对含碱金属氯化物较多的冶金粉尘在烧结工序中使用影响混匀矿烧结性能的问题,本文采用微型烧结试验,研究不同碱金属氯化物含量对铁矿粉高温烧结特性的影响.结果表明,烧结过程中碱金属氯化物与SiO2反应形成硅酸盐,抑制了复合铁酸钙的形成,导致铁矿粉最低同化温度增加.随着铁矿粉中碱金属氯化物的含量增加,铁矿粉液相数量下降,导致铁矿粉收缩高度和流动性指数均下降.当碱金属氯化物过多时,液相中K+和Na+数量增加使液相黏度降低,导致流动指数有少量增加.碱金属氯化物添加后烧结矿中大孔孔隙数量逐渐下降,使烧结矿黏结强度增加.
Effect of alkali metal chloride on sintering performance of iron ore at high temperature
In response to the problem of metallurgical dust containing a high amount of alkali metal chlorides affecting the sintering performance of mixed ore in the sintering process,micro sintering experiments were used in this paper to study the effect of different alkali metal chloride contents on the high-temperature sintering characteristics of iron ore powder.The result showed that the alkali metal chloride reacts with SiO2 to form a silicate during the sintering process,which inhibited the formation of composite calcium ferrite.It causes the minimum assimilation temperature of iron ore to increase.The amount of liquid phase of the iron ore powder decreased with the increase of the content of alkali metal chloride.This caused to decrease the shrinkage height and the fluidity index of the iron ore.When the alkali metal chloride was too much,the increase of the amount of K+and Na+in the liquid phase reduced the viscosity of the liquid phase so that led to a slight increase in flow index.The number of large pores in sintered ore gradually decreased with the addition of alkali chloride,which increased the sintered ore bond strength.

iron orealkali metalchloridehigh temperature characteristicsporosity

杨代伟、王炜、陈绪亨

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江苏永钢集团有限公司,江苏苏州 215628

武汉科技大学钢铁冶金及资源利用省部共建教育部重点试验室,湖北武汉 430081

铁矿粉 碱金属 氯化物 高温特性 孔隙率

国家自然科学基金资助项目国家自然科学基金资助项目

51974212U1760101

2024

烧结球团
中冶长天国际工程有限责任公司(原长沙冶金设计研究院)

烧结球团

北大核心
影响因子:0.322
ISSN:1000-8764
年,卷(期):2024.49(4)