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不同激发方法对钢渣胶凝材料活性提高及机理研究

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钢渣作为一种绿色、可回收利用的胶凝材料,因活性较低而限制了其应用价值.本文旨在研究不同的激发方法对钢渣胶凝活性的影响和作用机理,通过试验验证了碱激发、酸改性+碱激发、超声空化+碱激发3种方法对钢渣的活性提高效果,并探究了酸改性和超声空化对钢渣强度的影响机理.结果表明,酸改性主要提高前期强度,但甲酸钙的生成会消耗Ca(OH)2并导致环境的碱性降低,从而使得后期强度较为薄弱.相比之下,超声空化能够清除钢渣表面的惰性成分,促进C3S、C2S等活性物质的溶出和反应,从而加速水化反应和C—S—H胶凝物质形成,可更好地提高胶凝体系的强度.本文所采用的方法和研究结果可为钢渣处理和利用提供一些新的思路和方向.
Study on the enhancement and mechanisms of steel slag cementitious material activity by different activation methods
Steel slag is a green and recyclable cementitious material with limited application value due to its low activity.This paper aims to investigate the effects and mechanisms of different activation methods on the activity of steel slag,and to experimentally verify the effectiveness of three methods:alkaline activation,acid modification+alkaline activation,and ultrasonic cavitation+alkaline activation.This study also explores the effects of acid modification and ultrasonic cavitation on the strength development of steel slag.The results showed that acid modification mainly improves the early strength,but the generation of calcium formate consumes Ca(OH)2 and reduces the alkalinity of the environment,resulting in weaker later strength.In contrast,ultrasonic cavitation can remove the inert components on the surface of steel slag,promote the dissolution and reaction of active substances such as C3S and C2S,and accelerate the hydration reaction and formation of C—S—H gelling materia,thereby improving the strength of the cementitious system.The methods and results presented in this paper can provide new ideas and directions for the treatment and utilization of steel slag.

steel slag powderactivationmicroscopic mechanismcavitation effectacid modificationalkali activation

袁啸、赵慧玲

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上海大学力学与工程科学学院,上海 200444

钢渣粉 活性激发 微观机理 空化作用 酸改性 碱激发

国家自然科学基金资助项目

42277163

2024

烧结球团
中冶长天国际工程有限责任公司(原长沙冶金设计研究院)

烧结球团

北大核心
影响因子:0.322
ISSN:1000-8764
年,卷(期):2024.49(4)