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氮氧化物和二英低温脱除的锰基催化剂研究进展

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工业化进程推进中钢铁材料被大量使用,以钢铁为代表的行业快速发展并产生了多污染物复合排放问题.其中,氮氧化物(NOx)与二英(PCDD/Fs)是两种代表性污染物,而目前使用催化剂催化降解这两种污染物是最具潜力的方法.本文从各种锰基催化剂的制备、活性以及催化机理进行总结梳理,综述低温脱硝催化剂、低温脱二英催化剂、低温同时脱硝脱二英锰基催化剂的研究进展,阐述不同催化剂活性与制备条件的变化关系以及催化分解机理.锰基催化剂对NO,、二英以及两种污染物的协同脱除具有很高的研究价值与应用前景.
Advances on manganese-based catalysts for low-temperature removal of nitrogen oxides and dioxins
In the process of industrialization,steel materials are used in large quantities,and the rapid development of the industry represented by steel has produced the problem of multi-pollutant compound emissions.Among them,nitrogen oxides(NOx)and dioxins(PCDD/Fs)are two representative pollutants,and the catalytic degradation of these two pollutants by catalysts is the most promising method.In this paper,the preparation,activity and catalytic mechanism of various manganese-based catalysts are summarized,and the advances on low-temperature denitrification catalysts,low-temperature dioxin de-dioxin catalysts,and low-temperature simultaneous denitrification dioxin-based manganese-based catalysts are summarized,and the relationship between the activity of different catalysts and the preparation conditions and the catalytic decomposition mechanism are expounded.In this paper,the preparation,activity and catalytic mechanism of various manganese-based catalysts are summarized,and the research progress of low-temperature denitrification catalysts,low-temperature dioxin de-dioxin catalysts,and low-temperature simultaneous denitrification dioxin-based manganese-based catalysts is summarized,and the relationship between the activity of different catalysts and the preparation conditions and the catalytic decomposition mechanism are expounded.Manganese-based catalysts have high research value and application prospects for the synergistic removal of NOx,dioxins and two pollutants.

SCR methodNOxdioxinsmanganese-based catalystssynergistic removal

仲佳鑫、徐慕涛、陈利国、程鑫培、金奇杰、杨建、朱成章、徐海涛

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南通市海门区生态环境局,江苏南通 226100

南京工业大学材料科学与工程学院,江苏南京 211816

南京工业大学环境科学与工程学院,江苏南京 211816

SCR法 NOx 二英 锰基催化剂 协同脱除

2024

烧结球团
中冶长天国际工程有限责任公司(原长沙冶金设计研究院)

烧结球团

北大核心
影响因子:0.322
ISSN:1000-8764
年,卷(期):2024.49(6)