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嵌入式SCR球团烟气NOx排放升高原因及解决措施

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在钢铁行业推进超低排放的背景下,嵌入式SCR与SNCR耦合脱硝技术因脱硝效率高、性价比高等优势在球团烟气治理中得到推广应用.本文针对某工程项目安装嵌入式SCR脱硝装置达标排放后,NOx质量浓度经预热段再度升高的情况,系统分析NOx质量浓度升高的原因,并提出对应解决措施.结果表明:SCR脱硝后NOx质量浓度升高的原因并非由烟气侧漏或者混风所致,而是球团组分中的巴西粗粉以及掺入其中的硝酸清洗液在干燥预热过程中的热分解过程产生了NOx,两者的释放量占比分别为28.7%和58.9%.通过物料的程序升温测试发现,在460℃与650℃附近存在两处属于不同NOx来源的释放峰值,这与干燥Ⅱ段370℃及预热I段650℃的两股烟气的温度接近,造成NOx在该两处窗口温度附近快速释放.而嵌入式SCR脱硝技术是基于对各温度区间的余热进行充分利用而发展的高效脱硝工艺,故难以通过调整链箅机各段的温度区间来降低NOx释放量.基于此,本文提出通过替换过滤机硝酸清洗液的优化措施,使得NOx释放量显著降低,保障球团烟气达到超低排放标准.
Causes and solutions to the increase of NOx emissions from embedded SCR pellets gas
In the context of the promotion of ultra-low emissions in the iron and steel industry,the technology of embedded SCR and SNCR coupled denitrification has been popularized and applied in pellets gas treatment due to its high denitrification efficiency and high cost performance.The reasons for the increase of NOx mass concentration are systematically analyzed and corresponding solutions are proposed in view of the situation that the NOx mass concentration increases again through the preheating section after the embedded SCR denitrification device is installed in a certain engineering project.The results show that the increase of NOx mass concentration after SCR denitrification is not caused by gas leakage or air mixing,but by the thermal decomposition process of Brazilian coarse powder in the pellets component and the nitric acid cleaning solution mixed in it during the drying and preheating process,which accounts for 28.7%and 58.9%,respectively.Through the temperature-programmed test of the material,it is found that there are two peak NOx emission peaks belonging to different sources near 460 ℃ and 650 ℃,which are close to the temperature of the two gases at 370℃ in the drying Ⅱ section and 650 ℃ in the preheating I section,resulting in the rapid release of NOx near the temperature of the two windows.However,the embedded SCR denitrification technology is an efficient denitrification process developed based on making full use of the waste heat in each temperature range,so it is difficult to reduce the NOx emission by adjusting the temperature range of each section of the grate.Based on this,the optimization measures of replacing the nitric acid cleaning solution of the filter are proposed,so that the NOx emission can be significantly reduced,and the pellets gas can meet the ultra-low emission standard.

pelletsgasnitrogen oxidesembedded SCRdenitrification

李建军、熊劲、邵雁、汪远、潘春锋、向浩、刘子豪

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钢铁研究总院连铸技术国家工程研究中心,北京 100081

中国冶金科工股份有限公司,北京 100028

中冶南方都市环保工程技术股份有限公司,湖北武汉 430200

球团 烟气 氮氧化物 嵌入式SCR 脱硝

2024

烧结球团
中冶长天国际工程有限责任公司(原长沙冶金设计研究院)

烧结球团

北大核心
影响因子:0.322
ISSN:1000-8764
年,卷(期):2024.49(6)