首页|钝化修复在重金属污染农田中的应用

钝化修复在重金属污染农田中的应用

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某地重金属污染农田修复中,通过小区设计,对比分析了不同种类复配钝化剂的效果,第一年度筛选出了对土壤重金属活化态有明显抑制效果的"硅铝酸盐+有机质"和"磷酸盐+有机质"两种钝化剂组合.第二年度验证了"硅铝酸盐+磷酸盐+有机质"配方药剂组合分批投加最佳的养护老化时间为3~7天,老化时间超过7天,会造成硅铝酸盐、有机质成分的流失;不同有机质品种之间钝化效果的差异性不大,组合施加也无明显的协同作用.第三年度在相同的钝化剂配方和养护时间条件下,叶面阻控剂使用量增加不会对植物的重金属吸收量产生正向影响.通过扩大示范区,相较2019年小麦种植之前的背景调查结果,2020年小麦收割时土壤Cd总量浓度平均降低11.43%;2020~2021年间土壤Cd总量浓度继续下降,至2021年小麦收割时浓度平均降低12.14%;2021~2022年度Cd总量浓度有所回升,相较2019年,平均降低率回升到了5.19%,平均浓度约为1.88mg/kg.本试验的实施,为其他重金属污染农田中的钝化修复提供参考.
Application of Passivation Restoration in Heavy Metal Polluted Farmland
In the passivation restoration project of a heavy metal polluted farmland in Henan,the effects of different kinds of compound passivation agents were compared and analyzed through the design of the plot.In the first year,two passivating agent combinations of"silicoaluminate+organic matter"and"phosphate+organic matter",which have obvious inhibition effect on the activated state of heavy metals in soil,were screened out,and their passivating stability needs to be further verified.In the second year,it was verified that the optimal curing and aging time of"silicoaluminate+phosphate+organic matter"formula combination was 3-7 days,and the aging time was more than 7 days,which would cause the loss of silicoaluminate and organic matter components.There is little difference in passivation effect among different organic matter varieties,and there is no obvious synergistic effect in combination application.In the third year,under the same passivating agent formulation and curing time,the increase of the amount of foliar barrier agent did not have a positive effect on the heavy metal absorption of plants.By expanding the demonstration area,compared with the background survey results before wheat planting in 2019,the total soil Cd concentration during wheat harvesting in 2020 was reduced by an average of 11.43%;The total concentration of soil Cd continued to decrease from 2020 to 2021,and the average concentration decreased by 12.14%at the time of wheat harvest in 2021.The total concentration of cadmium in 2021-2022 has risen,and compared with 2019,the average reduction rate has risen to 5.19%,and the average concentration is about 1.88mg/kg.The implementation of this experiment can provide reference for passivation restoration projects in other heavy metal polluted farmland.

Passivation repairPassivating agentCadmium pollutionLead pollutionWheat kernel

钟天翔、王振平、杨建涛

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中节能大地环境修复有限公司,北京 100082

河南农业大学,河南 郑州 450002

钝化修复 钝化剂 镉污染 铅污染 小麦籽粒

2024

世界有色金属
有色金属技术经济研究院

世界有色金属

影响因子:0.138
ISSN:1002-5065
年,卷(期):2024.(15)
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