河北地质大学学报2024,Vol.47Issue(5) :1-7.DOI:10.13937/j.cnki.hbdzdxxb.2024.05.001

"独龙玉"的谱学特征及颜色成因研究

A Study on the Spectroscopic Characteristics and Color-Genesis of"Dulong Jade"

刘淑红 李芬香 康志娟 路峰 徐麟 刘雪婧
河北地质大学学报2024,Vol.47Issue(5) :1-7.DOI:10.13937/j.cnki.hbdzdxxb.2024.05.001

"独龙玉"的谱学特征及颜色成因研究

A Study on the Spectroscopic Characteristics and Color-Genesis of"Dulong Jade"

刘淑红 1李芬香 1康志娟 1路峰 1徐麟 1刘雪婧2
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作者信息

  • 1. 河北省地质实验测试中心,河北 保定 071051;河北省矿产资源与生态环境监测重点实验室,河北 保定 071051
  • 2. 河北资源环境职业技术学院,河北 石家庄 050083
  • 折叠

摘要

文章通过红外光谱、拉曼光谱、紫外-可见光光谱、电感耦合等离子体质谱(ICP-MS)等测试技术和薄片鉴定方法对"独龙玉"的矿物组成、显微结构、颜色成因进行了研究分析.结果表明"独龙玉"主要矿物为石英,次要矿物为鳞片状、少数呈片状铬云母及黄铁矿等,局部偶见土状褐黄色高岭石矿物沿石英颗粒间隙呈细脉状充填."独龙玉"的过渡金属元素中Cr、Ni、V含量较高,其绿色主要为Cr3+晶体场中八面体配位的两组电子跃迁所致.该研究为"独龙玉"的颜色成因造成的市场困扰提供了鉴别参考,为该玉石的科学鉴定提供了数据支持.

Abstract

In this paper,the mineral composition and color-genesis of"Dulong Jade"were examined and analyzed through testing techniques such as infrared absorption spectra,Raman spectra,UV-Vis spectra,ICP-MS and thin section identification.The results indicate that the main mineral of"Dulong jade"is quartz,the secondary minerals are flaky fuchsite,a few schistose fuchsite and pyrite;locally,earthy brown-yellow kaolinite minerals are filled as veinlets along the gaps between quartz particles occasionally.In"Dulong Jade",the transition metals of Cr,Ni,and V are relatively high.The result indicates that the green color of"Dulong Jade"is caused by two sets of electron transition in the octahedral coordination of Cr3+crystal field.This study clarifies the causes of"Dulong Jade"is color distribution,providing references for its the market identification,and provides scientific data for its scientific identification.

关键词

"独龙玉"/谱学特征/颜色成因/石英/铬云母

Key words

"Dulong Jade"/spectroscopic characteristics/color-genesis/quartz/fuchsite

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基金项目

保定市科技计划项目(2240ZZ007)

保定市科技计划项目(2341ZF166)

出版年

2024
河北地质大学学报
石家庄经济学院

河北地质大学学报

CHSSCD
影响因子:0.287
ISSN:1007-6875
参考文献量13
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