塑料2024,Vol.53Issue(5) :38-41,90.

磷钨酸银/PVA抗菌包装薄膜的制备及性能

Preparation and Properties of Phosphotungstate Silver/PVA Antibacterial Packaging Film

徐莉 丁艳红 王保营 康星雅 王建闯 张岩
塑料2024,Vol.53Issue(5) :38-41,90.

磷钨酸银/PVA抗菌包装薄膜的制备及性能

Preparation and Properties of Phosphotungstate Silver/PVA Antibacterial Packaging Film

徐莉 1丁艳红 1王保营 1康星雅 1王建闯 1张岩1
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作者信息

  • 1. 河南牧业经济学院,河南,郑州 450046
  • 折叠

摘要

以磷钨酸银为抗菌剂、聚乙烯醇(PVA)为成膜基材,采用流延法制备一种兼具较好力学性能及抗菌性能的磷钨酸银/PVA复合薄膜,分析复合薄膜的力学性能、水蒸气透过率及抗菌性能.实验结果表明,随着磷钨酸银含量的增加,力学性能逐渐增大,当磷钨酸银的含量为1 g时,拉伸强度达到最大,其值为75.6 MPa,与PVA纯膜相比,拉伸强度提高了 128.3%;随磷钨酸银含量的增大,水蒸气透过率逐渐增大,由0.5 ×10-14 g/(cm2·s·Pa)增大至0.59 × 10-14 g/(cm2·s·Pa),提高了 16.1%;SEM测试结果表明,当磷钨酸银含量低于1 g时,磷钨酸银在PVA薄膜中分布均匀.同时,抑菌圈测试结果表明,复合薄膜对金黄色葡萄杆菌及大肠杆菌均具有较好的抑菌作用.

Abstract

A phosphotungstic acid silver/PVA composite film was prepared with silver phosphotungstic acid as the antibacterial agent and polyvinyl alcohol(PVA)as the film-forming substrate by flow casting method,which showed good mechanical and antibacterial properties.The mechanical properties,water vapor transmission rate and antibacterial properties of the composite film were studied.The experimental results showed that mechanical properties gradually increased with the increase of silver phosphotungstate content.When the content of silver phosphotungstate was 1 g,the tensile strength was the highest,the highest value was 75.6 MPa.Compared with PVA pure film,the tensile strength increased by 128.3%;The water vapor transmission rate gradually increases with the increase of silver phosphotungstate content,from 0.5 × 10-14 g/(cm2·s·Pa)to 0.59 × 10-14 g/(cm2·s·Pa),which was increased 16.1%compared with PVA pure film;SEM testing showed that when the content of silver phosphotungstate was less than 1 g,the distribution of silver phosphotungstate in PVA film was uniform.Meanwhile,the results of the antibacterial zone test showed that the composite film had good antibacterial effects on Staphylococcus aureus and Escherichia coli.

关键词

磷钨酸银/聚乙烯醇/包装薄膜/抗菌性能/力学性能

Key words

phosphotungstate silver/polyvinylalcohol/packaging film/antibacterial property/mechanical property

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基金项目

河南省重点研发与推广专项(科技攻关)项目(232102321039)

河南牧业经济学院博士科研启动基金(2020HNUAHEDF023)

出版年

2024
塑料
北京市塑料研究所

塑料

CSTPCDCSCD北大核心
影响因子:1.163
ISSN:1001-9456
参考文献量16
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