塑料2024,Vol.53Issue(5) :57-61,107.

Ni含量对CrNiN涂层结构及抗粘耐蚀性能的影响

Effect of Ni Content on Structure and Anti-Stick Corrosion Resistance of CrNiN Coating

王胜利 赵中里 张齐松 吴大鸣 许红 薛勇杰
塑料2024,Vol.53Issue(5) :57-61,107.

Ni含量对CrNiN涂层结构及抗粘耐蚀性能的影响

Effect of Ni Content on Structure and Anti-Stick Corrosion Resistance of CrNiN Coating

王胜利 1赵中里 1张齐松 2吴大鸣 1许红 1薛勇杰3
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作者信息

  • 1. 北京化工大学,北京 100029
  • 2. 中国兵器工业集团江山重工研究院有限公司,湖北,襄阳 441057
  • 3. 北京机械工业自动化研究所,北京 100032
  • 折叠

摘要

为了提高塑料机械螺杆的抗粘耐蚀性能,采用多弧离子镀技术在38CrMoAl基体上制备了不同Ni含量的NiCrN涂层,系统研究了 Ni含量对涂层结构、硬度、抗粘性能以及耐蚀性能的影响.结果表明,制备的涂层层间界面清晰完整,主要由Ni相、Cr2N及CrN陶瓷相组成.随着涂层中Ni含量增加,涂层与基体结合更加牢靠,而接触角呈现先降低后升高趋势,当Ni含量为7.65%时,达到最大值.盐雾腐蚀实验和电化学腐蚀实验结果表明,Ni含量为7.65%的涂层耐蚀效果最好.当Ni含量为7.65%时,CrNiN涂层具有最佳的综合性能,有效地提高了注塑机螺杆、注塑模具的使用寿命.

Abstract

In order to improve the anti-stick and corrosion resistance of plastic mechanical screws,NiCrN coatings with different Ni content were prepared on 38CrMoAl matrix by multi-arc ion plating technology,and the effects of Ni content on coating structure,hardness,anti-stick performance and corrosion resistance were systematically studied.The results showed that the interface between the layers of the prepared coating was clear and complete,and it was mainly composed of Ni phase,Cr2N and CrN ceramic phase.With the increase of Ni content in the coating,the bond between the coating and the matrix was more firm,and the contact angle showed a trend of first decreasing and then increasing,reaching a maximum when the Ni content was 7.65%.The results of salt spray corrosion experiment and electrochemical corrosion experiment showed that the coating with Ni content of 7.65%had the best corrosion resistance.The CrNiN coating with Ni content of 7.65%had the best comprehensive performance,which effectively improved the service life of the injection molding machine screw and injection mold.

关键词

螺杆/PVD/NiCrN涂层/微观结构/抗粘耐蚀

Key words

screw/PVD/NiCrN coating/microstructure/anti-adhesive and corrosion-resistant

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基金项目

安徽省重点研究与开发计划(202004a05020024)

出版年

2024
塑料
北京市塑料研究所

塑料

CSTPCD北大核心
影响因子:1.163
ISSN:1001-9456
参考文献量10
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