塑料2024,Vol.53Issue(5) :108-112.

聚丙烯成核剂的开发与进展

Development and Progress of Nucleating Agent for Polypropylene

张咪 林福华
塑料2024,Vol.53Issue(5) :108-112.

聚丙烯成核剂的开发与进展

Development and Progress of Nucleating Agent for Polypropylene

张咪 1林福华2
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作者信息

  • 1. 太原科技大学,材料科学与工程学院,山西,太原 030024;山西省化工研究所(有限公司),山西,太原 030600
  • 2. 山西工程科技职业大学,山西,晋中 030606
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摘要

聚丙烯(PP)是一种典型的半结晶热塑性聚合物,由于PP熔体的结晶速率较慢,易形成较大尺寸的球晶,其制品的光泽度和透明性较差,限制了 PP在透明包装和日用品等领域的发展.目前,主要通过改变PP晶型的结晶行为达到改性PP的目的;而成核剂与PP共混改性在保留了 PP原有特点的同时,透明性济表面光泽度均得到明显改善,为PP改性常用的方法.基于此,总结了 PP结晶的机理,并且,综述了目前PP成核剂的研究现状,涉及的α成核剂种类包括无机类、枞酸类、环状羧酸盐类、山梨醇缩醛类及磷酸酯盐类成核剂;β成核剂种类包括稠环类、二元羧酸盐类、酰胺类、稀土类成核剂及复配型成核剂.

Abstract

Polypropylene is a typical semi-crystalline thermoplastic polymer.Due to the slow crystallization rate of PP melt,it is easy to form big spherulites,resulting in poor gloss and transparency of products,which limits the development of PP in the fields of transparent packaging and daily necessities.At present,most of the modification methods for PP are focused on changing the crystallization behavior of PP crystal.The blending of nucleating agents and PP not only retains the original advantages of PP,but also significantly improves the transparency and surface gloss,which is a common means of PP modification.Based on this,summarize the mechanism of PP crystallization and review the current research status of PP nucleating agents.The types of α nucleating agents are included inorganic nucleating agents,abietic acid nucleating agents,cyclic carboxylate nucleating agents,sorbitol acetal nucleating agents and phosphate ester nucleating agents.The types of βnucleating agents are included fused ring nucleating agents,dicarboxylate nucleating agents,amide nucleating agents,rare earth nucleating agents and compound nucleating agents.

关键词

聚丙烯/成核剂/结晶理论/改性/应用性能

Key words

polypropylene/nucleating agent/crystallization theory/modification/application property

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基金项目

山西省科技成果转化引导专项基金(202104021301027)

出版年

2024
塑料
北京市塑料研究所

塑料

CSTPCD北大核心
影响因子:1.163
ISSN:1001-9456
参考文献量4
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