塑料2024,Vol.53Issue(6) :16-22,27.

PBT绝缘导热复合材料的性能及制备

Properties and Preparation of PBT Insulating and Thermally Conductive Composite

张宁 滕业方 赵东 汪称意
塑料2024,Vol.53Issue(6) :16-22,27.

PBT绝缘导热复合材料的性能及制备

Properties and Preparation of PBT Insulating and Thermally Conductive Composite

张宁 1滕业方 1赵东 1汪称意2
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作者信息

  • 1. 常州工业职业技术学院,材料工程学院,江苏,常州 213000
  • 2. 常州大学,材料科学与工程学院,江苏,常州 213000
  • 折叠

摘要

随着电子技术的发展,高集成和小型化电子器材在高频工作条件下产生的热量迅速累积,对其散热能力提出了更高的要求.因此,设计并合成一种具有优良绝缘导热性能的材料对电子技术发展具有重要意义,其中具备较好的绝缘和加工性能的聚合物材料在微电子技术和高集成电路等领域得到人们的广泛关注.以聚对苯二甲酸丁二醇酯(PBT)为连续相,改性氮化硼(BN-PDA)、多壁碳纳米管(MWCNTs)等导热填料为分散相,制备了绝缘导热复合材料.实验结果表明,PBT/BN-PDA/MWCNTs复合材料内部形成了三维导热网络结构,与PBT/BN-PDA@MWCNTs复合材料相比,其导热能力较好.添加20%BN与4%MWCNTs的PBT/BN-PDA/MWCNTs复合材料的综合性能最佳,热导率为0.94 W/(m·K),与纯PBT相比,提升了223.90%,并且,满足电气绝缘导热的要求.

Abstract

With the continuous development of electronic technology,the heat generated by highly integrated and miniaturized electronic devices under high-frequency working conditions accumulates rapidly,which put forward higher requirements for their heat dissipation capabilities.Therefore,the design and synthesis of a material with excellent insulating and thermal conductivity was of great significance for the development of electronic technology.Polymer materials with excellent insulation and processing properties had attracted a lot of attention in the fields of microelectronics technology and high integrated circuits.The insulating and thermal conductive composite were prepared with polybutylene terephthalate(PBT)as the continuous phase,modified Boron nitride(BN-PDA),multi wall carbon nanotubes(MWCNTs)and other thermal conductive fillers as the dispersed phase.The experimental results indicated that a three-dimensional thermal conductivity network structure was formed inside the PBT/BN-PDA/MWCNTs composite,and the thermal conductivity was slightly higher than that of the PBT/BN-PDA@MWCNTs composite.The PBT/BN-PDA/MWCNTs composite material with 20%BN and 4%MWCNTs had the best comprehensive performance,with a thermal conductivity coefficient of 0.94 W/(m·K),which was not only 223.90%higher than pure PBT,but also met the electrical insulation and thermal requirements.

关键词

聚对苯二甲酸丁二醇酯/氮化硼/多壁碳纳米管/绝缘导热/三维导热网络

Key words

polybutylene terephthalate/boron nitride/multi walled carbon nanotubes/insulation thermal conductivity/three-dimensional thermal conductivity network

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出版年

2024
塑料
北京市塑料研究所

塑料

CSTPCDCSCD北大核心
影响因子:1.163
ISSN:1001-9456
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