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TBCL的合成及其在尼龙6中的应用

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以对苯二甲酰氯和己内酰胺为原料,通过无机碱中和制得目标产物对苯二甲酰双己内酰胺(TBCL),反应过程不产生有机盐废水,反应条件温和.再通过双螺杆挤出机熔融共混制备了TBCL/尼龙6(PA6)共混物.通过红外光谱(FTIR)和差示扫描量热仪(DSC)对TBCL进行结构表征,通过转矩流变仪、万能拉力机与数位冲击仪等考察了TBCL对PA6 流变性能、力学性能和热稳定性的影响.结果表明,加入TBCL后,PA6 共混物的流动性下降,冲击强度与热变形温度提高.随着添加量的增加,弯曲模量下降幅度不大,但冲击强度则持续提升,基本实现了PA6 刚性几乎不损失的情况下韧性显著提高.
Synthesis of TBCL and Its Application in Nylon 6
Using phenylphthalyl chloride and caprolactam,the target product parylene dimethyldicaprolactam(TBCL)was neutralized by inorganic alkali.The reaction process did not produce organic salt wastewater,and the reaction conditions were mild.Furtherly TBCL/nylon 6(PA6)blend was prepared by twin screw extruder melt blending process.TBCL was structurally characterized by means of Fourier transform infrared spectroscopy(FTIR)and differential scanning calorimeter(DSC).The effects of TBCL on the rheology,mechanical properties and thermal stability of nylon 6 were investigated by torque rheometer,universal tension machine and digital impact ometer.The results show that the fluidity of nylon 6 blend decreases after the addition of TBCL mixture,and the shock strength increases with the thermal deformation temperature.With the increase of the added amount,the bending modulus does not much,but the impact strength continues to improve,which basically improves the toughness of nylon 6 without any loss of rigidity.

Terephthaloyl Bis-caprolactamNylon 6Chain ExtensionMechanical Property

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山西省化工研究所 (有限公司), 山西 太原 030600

对苯二甲酰双己内酰胺 尼龙6 扩链 力学性能

山西省省属转制科研院所科研条件提升专项山西省重点研发计划

202102040201004

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(1)
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