塑料工业2024,Vol.52Issue(2) :71-78.DOI:10.3969/j.issn.1005-5770.2024.02.011

特种工程塑料对环氧树脂的改性作用

Modification Effect of Special Engineering Plastics on Epoxy Resin

周建文 易荣军 柯杰曦 王洪 孙通 刘海燕 胡江
塑料工业2024,Vol.52Issue(2) :71-78.DOI:10.3969/j.issn.1005-5770.2024.02.011

特种工程塑料对环氧树脂的改性作用

Modification Effect of Special Engineering Plastics on Epoxy Resin

周建文 1易荣军 1柯杰曦 1王洪 1孙通 1刘海燕 2胡江2
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作者信息

  • 1. 中蓝晨光化工有限公司,四川成都 610041
  • 2. 中蓝晨光化工研究设计院有限公司,四川成都 610041
  • 折叠

摘要

研究了聚醚醚酮(PEEK)、聚酰亚胺(PI)、热塑性聚酰亚胺(TPI)、聚苯硫醚(PPS)、聚砜(PSF)、液晶高分子聚合物(LCP)和聚芳酯(PAR)等特种工程塑料对环氧树脂力学热学和电性能改性效果.具有刚性基元及活性基元的工程塑料在环氧固化过程中产生微分相,吸收应力作用下的能量,阻止微裂纹扩散,对环氧树脂力学性能(拉伸、压缩、冲击强度)有提升作用;耐热性优于环氧的特种工程塑料对提高环氧耐热性有益,在固化过程中与环氧树脂产生分子间作用力引起耐热性进一步提高;绝缘性更佳的工程塑料改性环氧后绝缘性能提高.分散性差的PSF聚集形成弱界面层,受力作用下首先破坏,主要力学性能稍有降低.LCP与PAR难以在环氧树脂中形成均一相,不能用于环氧树脂改性研究.

Abstract

The effects of special engineering plastics,such as,polyether ether ketone(PEEK),polyimide(PI),thermoplastic polyimide(TPI),polyphenylene sulfide(PPS),polysulfone(PSF),liquid crystal polymer(LCP),polyarylester(PAR)on the mechanical thermal and electrical properties of epoxy resins were studied in this paper.The engineering plastics with rigid and active elements produced differential phase in the epoxy curing process,which could absorb energy under stress,prevent microcrack diffusion,and improve the mechanical properties of epoxy resin,including tensile,compression and impact strength.Special engineering plastics with better heat resistance than epoxy resins are beneficial for improving the heat resistance of epoxy resins.During the epoxy curing process,strong intermolecular forces are generated between special engineering plastics and epoxy resin,which further enhances the heat resistance of modified epoxy resins.Better insulation of epoxy resin are achieved by adding engineering plastics with fine insulation equipment.PSF with poor dispersibility aggregates to form a weak interface layer,which first fails under stress,and its main mechanical properties slightly decrease.LCP and PAR are difficult to form a homogeneous phase in epoxy resin and cannot be used for epoxy resin modification research.

关键词

环氧树脂/力学性能/特种工程塑料/热性能/电性能

Key words

Epoxy Resin/Mechanical Property/Special Engineering Plastics/Thermal Performance/Electrical Performance

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出版年

2024
塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
参考文献量15
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