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壳聚糖-聚丙烯酸磁性水凝胶制备及Cu2+吸附

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水中的重金属离子污染的危害性巨大,并且治理相对比较困难,是当今环境保护的一大难题.通过两步法,制备了物理交联的钴铁粒子-壳聚糖-聚丙烯酸-甲壳素(CoFe2 O4-CS-PAA-CT)多重互穿网络磁性水凝胶,并对水凝胶的结构、热稳定性、磁性、吸附性能和再生性进行了研究.该CoFe2 O4-CS-PAA-CT水凝胶具有良好的自修复性、再生性和吸附性,对Cu2+的饱和吸附量为247.22 mg/g.CoFe2 O4-CS-PAA-CT水凝胶在吸附重金属离子时,重金属离子浓度越高,吸附量越高;pH值≤5.0时,吸附效果最好;干扰离子浓度增大会降低水凝胶的吸附量.研究表明CoFe2 O4-CS-PAA-CT多重互穿网络水凝胶能够作为未来处理重金属污水的一种新的选择.
Preparation of Chitosan-Polyacrylic Acid Magnetic Hydrogels and Adsorption of Cu2+
Heavy metal ion pollution in water is very harmful,and it is relatively difficult to control,which is a major problem in environmental protection today.In this study,the physical cross-linked magnetic hydrogels with multiple interpenetrating networks based on Co-Fe particle-chitosan-polyacrylate-chitin(CoFe2 O4-CS-PAA-CT)were prepared by a two-step method.The structures,thermal stability,magnetic property,adsorption property and regeneration of the hydrogels were studied.The results show that the CoFe2 O4-CS-PAA-CT hydrogel has good self-healing,regeneration and adsorption,and the saturation adsorption capacity for Cu2+is 247.22 mg/g.When CoFe2 O4-CS-PAA-CT hydrogel adsorbs heavy metal ions,the higher the concentration of heavy metal ions,the higher the adsorption capacity.When the pH value is no more than 5.0,the adsorption effect is the best.The adsorption capacity of hydrogel decreases with the increasing of interfering ion concentration.The multiple interpenetrating network hydrogels based on CoFe2 O4-CS-PAA-CT can be used as a new option to treat heavy metal wastewater in the future.

ChitosanAcrylic AcidHeavy Metal Ion AdsorptionMagnetic Hydrogel

李艳丽、黄成、崔译文、黄子诺、陈靖宇

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东南大学成贤学院制药与化学工程学院,江苏 南京 210088

壳聚糖 丙烯酸 重金属吸附 磁性水凝胶

江苏省高等学校自然科学研究项目东南大学成贤学院大学生创新项目

20KJB430044XCX23102

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(4)
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