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空间电场作用下聚合物形貌演变及光学性能研究

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聚合物薄膜表面的微纳结构具有独特的光学性能,在柔性电子和显示器件中有潜在的应用前景.而空间电场是构建表面形貌的有效手段.本研究以光固化聚氨酯(PU)为对象,用comsol软件模拟了空间电场作用下PU预聚体的介电常数、黏度、表面张力、电压对形貌的影响.进一步通过实验,在600 V空间电场制备出高度为327 μm的柱状阵列微结构PU透明薄膜.该薄膜在380~750 nm波段,其出光效率提升了18%,且微结构对色温没有影响.
Morphological Evolutions and Optical Properties of Polymers in the Space Electric Field
The micro-nano structures of the polymer film surfaces have unique optical properties,which have potential applications in flexible electronics and display devices.The space electric field is an effective method to construct the surface morphology.The object of this study was photocurable polyurethane(PU),the comsol software was used to simulate the effects of dielectric constant,viscosity,surface tension,and voltage on the morphology of PU prepolymer in the space electric field.The results show that the PU transparent film containing columnar array microstructures with a height of 327 μm is prepared in a space electric field of 600 V.In the band of 380-750 nm,the luminous efficiency of the film is 18%higher than that before the film is placed,and the microstructures have no effect on the color temperature.

Space Electric FieldPolyurethane FilmMicrostructureAnalogue SimulationLuminous Efficiency

刘少琛、刘学清

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江汉大学光电材料与技术学院,光电化学材料与器件教育部重点实验室,湖北 武汉 430056

空间电场 聚氨酯薄膜 微结构 仿真模拟 出光效率

国家重点研发计划江汉大学重大创新支持计划湖北省创新团队项目

2022YFB36037022023ZDCX01T201935

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(5)