首页|基于极化-去极化电流法的老化PVC电缆绝缘性研究

基于极化-去极化电流法的老化PVC电缆绝缘性研究

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电缆老化会使绝缘失效,导致短路乃至火灾事故的发生.为研究低压电缆老化后的绝缘性能,对电缆中采用的聚氯乙烯(PVC)绝缘材料进行加速老化实验,通过对样本极化-去极化的电流数据进行分析,得到直流电导率、低频介质损耗因数等参数的变化规律,并利用热失重和傅里叶红外光谱测试老化样本的理化性能.结果表明,随着老化时间的增加,极化电流、去极化电流、电导率和低频介质损耗因数均增大.热失重分析和傅里叶红外光谱分析结果则进一步表明,长时间的高温老化会使PVC电缆绝缘的氯含量减少,阻燃性降低,PVC分子链断裂,羟基、甲基、亚甲基和C—C等官能团含量增加,电缆老化加剧,最终导致电缆的绝缘性下降.
Insulation Property Researches of Aged PVC Cables by the Polarization-Depolarization Current Method
The aging of electrical cables could lead to insulation breakdown,culminating in short circuits and even the occurrence of fire incidents.To investigate the insulating properties of low-voltage cables after aging,accelerated aging experiments were conducted on the polyvinyl chloride(PVC)insulation material used in the cables.Analysis of the polarization-depolarization current data from the samples revealed the change patterns in parameters such as DC conductivity and low-frequency dielectric loss factors.Furthermore,the physicochemical properties of the aged samples were assessed through thermogravimetric analysis and Fourier infrared spectroscopy.The results indicate that with the increase of aging time,there is a notable augmentation observed in parameters including polarization current,depolarization current,conductivity,and low-frequency dielectric loss factor.The thermal gravimetric analysis and Fourier transform infrared spectroscopy results further elucidate that the long-term high-temperature aging reduces the chlorine content of PVC cable insulation,diminishing the flame retardancy and resulting to the fracture of PVC molecular chains.The contents of functional groups such as hydroxyl,methyl,methylene,and carbon-carbon double bonds increase.These alterations exacerbate the cable aging,ultimately decreasing the insulation performances of cables.

Polarization-Depolarization Current MethodPolyvinyl Chloride CablesInsulating PropertyConductivityLow-frequency Dielectric Loss

温才权、韦鑫、王杰、周凯、李轩毅、龚薇、黎柏城、李亚伟

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中国南方电网有限责任公司超高压输电公司梧州局,广西 梧州 543000

四川大学电气工程学院,四川 成都 610065

西南民族大学电气工程学院,四川 成都 610041

极化-去极化电流法 聚氯乙烯电缆 绝缘性 电导率 低频介损

中国南方电网科技项目资助成都市技术创新研发项目国家自然科学基金项目

010500KK522200022022-YF05-00971-SN52277156

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(8)
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