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湿热环境对环氧树脂基复合材料拉伸性能的影响

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采用加速吸湿法得到玻璃纤维/L285 环氧树脂基复合材料吸湿特性曲线,通过对比分析湿热处理前后的化学结构、断口微观形貌以及力学性能,研究了湿热环境对玻璃化转变温度、损伤机理、抗拉强度以及弹性模量的影响,探究湿热老化机制,为通用航空飞机的安全运行提供理论和实验依据.结果表明,该复合材料吸湿初期符合Fick第二定律,后期吸湿曲线逐渐趋于平缓,湿度一定时,温度越高,吸湿率越大,达到吸湿饱和时间越长.水浴温度由 25℃增加到 85℃时,饱和吸湿率增加209%,相应吸湿饱和时间增加46.50%;湿热处理后复合材料的拉伸断裂失效形式发生改变,抗拉强度降低30.97%,弹性模量在6%范围内波动,加载初期应力—应变曲线呈线性关系,后期呈非线性变化趋势;相对25℃干态试样,85℃湿态试样的玻璃化转变温度下降24℃,相应的化学结构未发生变化,但纤维-基体界面发生了不可逆的物理变化.
Effects of the Hygrothermal Environments on the Tensile Properties of Epoxy Resin Composites
The moisture absorption characteristic curves of the glass fiber/L285 epoxy resin composites were obtained by the accelerated hygroscopic method.The effects of the hygrothermal environments on the glass transition temperature,damage mechanism,tensile strength and elastic modulus were investigated by comparing and analyzing the chemical structures,fracture microscopic morphologies,and mechanical properties before and after hygrothermal treatments.The hot-humid aging mechanisms were explored,providing theoretical and experimental basis for the safe operation of general aviation aircraft.The results show that the composite materials conform to the Fick's second law at the early stage of moisture absorption,and the moisture absorption curves gradually tend to flatten at the later stage.When the humidity is certain,the higher the temperature,the higher the moisture absorption rate,and the longer the time to reach the moisture absorption saturation.When the bath temperature is increased from 25℃to 85℃,the moisture saturation rate is increased by 209%,and moisture saturation time is increased by 46.50%.After the hygrothermal treatments,the tensile fracture failure form of the composite material changes,the tensile strength is reduced by 30.97%,and the elastic modulus fluctuates in the range of 6%.In the early stage of loading,the stress-strain curves are linear and show non-linear trends in the later period.Compared with the 25℃dry sample,the glass transition temperature of the 85℃wet sample is decreased by 24℃,the corresponding chemical structures do not change,but the fiber-matrix interfaces undergo irreversible physical changes.

Hygrothermal EnvironmentGlass Fiber Reinforced Resin CompositeDamage MechanismMechanical PropertyEpoxy Resin

康沁莹、陈淑仙、崔潇俊、代振帮

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中国民用航空飞行学院航空工程学院,四川 广汉 618307

中国民用航空飞行学院,四川省通用航空器维修工程技术研究中心,四川 广汉 618307

中国民用航空飞行学院广汉分院,四川 广汉 618307

湿热环境 玻璃纤维增强树脂基复合材料 损伤机理 力学性能 环氧树脂

国家自然科学基金民航联合基金重点资助项目四川省科技计划项目四川省通用航空器维修工程技术研究中心资助课题

U13332012019YJ0722GAMRC2021YB10

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(9)
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