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摩擦电用纳米填料/PDMS复合薄膜的性能

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摩擦纳米发电机为能源收集和传感监测提供了新的方向,摩擦层材料的高输出性能至关重要.本文研究了不同原料配比对聚二甲基硅氧烷(PDMS)拉伸性能的影响,以及不同无机填料(二氧化硅、二氧化钛、石墨、埃洛石纳米管)和二氧化钛填充浓度对PDMS薄膜电学性能和拉伸性能的影响.研究结果表明,固化剂的质量分数对PDMS的拉伸性能产生了一定影响,在应变达到100%内呈现弹性变形,4 种无机填料在不同程度上提高了PDMS的电输出性能,其中二氧化钛/PDMS复合薄膜的电输出性能最优.当二氧化钛的质量占PDMS质量的百分比为8%,电性能测量平台工作频率为2Hz时,二氧化钛/PDMS复合薄膜的最高开路电压达到160 V,较纯PDMS薄膜提高了8.4 倍,拉伸性能也最优.该研究为纳米填料提升PDMS薄膜性能提供了一定的参考.
Properties of Triboelectric Nanofiller/PDMS Composite Films
Triboelectric nanogenerators provide a new direction for energy harvesting and sensor monitoring.The high output performance of frictional layer materials is crucial.This study investigated the influences of different raw material ratios on the tensile properties of polydimethylsiloxane(PDMS),as well as the effects of various inorganic fillers(silica,titanium dioxide,graphite,halloysite nanotubes)and titanium dioxide filler concentrations on the electrical and tensile properties of PDMS films.The results show that the curing agent mass fraction has a certain impact on the tensile properties of PDMS,exhibiting elastic deformation within 100%strain.The four types of inorganic fillers enhance the electrical output performance of PDMS in different degrees.Among them,the titanium dioxide/PDMS composite film exhibits the best electrical output performance.When the mass of titanium dioxide accounts for the PDMS mass percentage of 8%and the working frequency of the electrical performance measurement platform is 2 Hz,the highest open-circuit voltage of titanium dioxide/PDMS composite film reaches 160 V,which is 8.4 times higher than that of pure PDMS film.This titanium dioxide/PDMS composite film also shows optimal tensile properties.This study provides references for improving the properties of PDMS films with nanofillers.

PolydimethylsiloxaneTriboelectric NanogeneratorCompositeMechanical PropertyElectrical Output PerformanceTitanium Dioxide

薛峰、贾非、王泽鹏、廖晨茜

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大连理工大学化工海洋与生命学院,辽宁 盘锦 124221

聚二甲基硅氧烷 摩擦纳米发电机 复合材料 拉伸性能 电输出性能 二氧化钛

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(9)
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