塑料工业2024,Vol.52Issue(9) :162-169.DOI:10.3969/j.issn.1005-5770.2024.09.024

乙基纤维素/明胶/香芹酚/金属有机框架湿度响应抗真菌纤维膜的制备及性能

Preparation and Properties of Ethyl Cellulose/Gelatin/Carvacrol/Metal-Organic Frame Humidity-Responsive Anti-fungal Fiber Films

朱柯宇 蒋晓倩 干莹莹 赵玉萍 刘耀文
塑料工业2024,Vol.52Issue(9) :162-169.DOI:10.3969/j.issn.1005-5770.2024.09.024

乙基纤维素/明胶/香芹酚/金属有机框架湿度响应抗真菌纤维膜的制备及性能

Preparation and Properties of Ethyl Cellulose/Gelatin/Carvacrol/Metal-Organic Frame Humidity-Responsive Anti-fungal Fiber Films

朱柯宇 1蒋晓倩 1干莹莹 1赵玉萍 1刘耀文1
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作者信息

  • 1. 四川农业大学食品学院,四川 雅安 625014
  • 折叠

摘要

为获得具有湿度响应的抗真菌纤维膜,实验以乙基纤维素(EC)和明胶(GEL)负载具有湿度响应的金属有机框架(MOF)铜金属有机框架(FH)纳米粒子和抑菌精油香芹酚(CAR),通过静电纺丝技术制备得到GEL/EC/CAR/FH湿度响应纤维膜,测试纤维膜的综合性能,并对膜中CAR的控释行为进行释放研究.结果表明,低质量分数(<4%)的FH纳米粒子对纤维膜的微观结构影响较小且在纤维膜内分布均匀.FH纳米粒子和CAR的添加改善了纤维膜的拉伸性能,同时使纤维膜具有一定的抗真菌性、抗氧化性.湿度响应控释性研究表明FH纳米粒子可以通过调节湿度对纤维膜上的CAR进行控释,当加入4%质量分数的FH时,50%~90%湿度变化下,CAR释放率(V)由60.58%±0.23%增加到 99.68%±0.08%,GEL/EC/CAR/FH湿度响应抗真菌纤维膜性能优良,控释效果良好.

Abstract

To obtain humidity-responsive antifungal fiber films,the experiment loaded humidity-responsive metal-organic framework material(MOF)copper metal-organic framework(FH)nanoparticles and bacteriostatic essential oil carvacrol(CAR)with ethyl cellulose(EC)and gelatin(GEL).The GEL/EC/CAR/FH humidity-responsive fiber films were prepared by electrospinning technology,the comprehensive properties of the fiber films were tested,and the controlled release behavior of CAR in the membrane was studied.The results show that the FH nanoparticles with a low mass fraction(<4%)have small effects on the microstructures of the fiber films and distribute uniformly in the fiber films.The addition of FH nanoparticles and CAR improves the tensile properties of the fiber films,and makes the fiber film have certain anti-fungal and anti-oxidation properties.The humidity response-control release study shows that FH particles could control the release of CAR on the fiber films by adjusting the humidity.When the mass fraction of FH nanoparticles is 4%,the CAR release rate(V)increases from 60.58%±0.23%to 99.68%±0.08%under the humidity change of 50%-90%.The GEL/EC/CAR/FH humidity-responsive anti-fungal fiber films have good performances,showing a good controlled release effect.

关键词

湿度响应/乙基纤维素/明胶/香芹酚/金属有机框架

Key words

Humidity Response/Ethyl Cellulose/Gelatin/Carvacrol/Metal Organic Frame

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出版年

2024
塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
参考文献量5
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