首页|HZSM-5催化生物质与废塑料协同热解制取苯系物研究进展

HZSM-5催化生物质与废塑料协同热解制取苯系物研究进展

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苯系物是一类重要的化工原料和燃料添加剂,具有广泛的工业应用和经济价值,主要来源于化石燃料.生物质与废塑料协同热解可以有效制取苯系物且具有废物利用和环境保护等优点.本文综述了氢交换索康美孚沸石-5(HZSM-5)催化生物质与废塑料协同热解制取苯系物研究进展,首先讨论了生物质与废塑料在无催化剂条件下直接制取苯系物的特点;然后重点论述了基于HZSM-5催化剂、金属改性HZSM-5、碱/碱土金属耦合HZSM-5以及不同催化方式制取苯系物的途径;通过金属改性、碱/碱土金属耦合以及催化方式可提高苯系物选择性和产率.本文为生物质和废塑料的高效催化转化提供一定的参考.
Research Progress of the Synergistic Pyrolysis of Biomass and Waste Plastics Catalyzed by HZSM-5 to Produce Benzene Series
Benzene series(BTEXs)mainly derived from fossil fuels is an important class of chemical raw materials and fuel additives with wide industrial applications and economic values.Synergistic pyrolysis of biomass and waste plastics could effectively produce BTEXs and has the advantages of waste utilization and environmental protection.This paper reviewed the research progresses of BTEXs produced by the synergistic pyrolysis of biomass and waste plastics catalyzed by the hydrogen exchanged zeolite socony mobil-5(HZSM-5).Firstly,the characteristics of directly-produced BTEXs from biomass and waste plastics without the catalyst were discussed.Then,the methods for producing BTEXs based on the HZSM-5 catalyst,metal-modified HZSM-5,alkali/alkaline earth metal coupled HZSM-5,and different catalytic methods were discussed.The selectivity and yield of BTEXs could be improved by metal modification,alkali/alkaline earth metal coupling,and catalytic methods.This paper provided some references for the efficient catalytic conversions of biomass and waste plastics.

BiomassWaste PlasticsCo-pyrolysisModified Hydrogen Exchanged Zeolite Socony Mobil-5Benzene Series

徐楠、王志伟、陈高峰、郭帅华、张婷婷、张焱鹏

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河南工业大学环境工程学院,河南 郑州 450001

河南工业大学碳中和研究院,河南 郑州 450001

中国三峡集团北京分公司,北京 100035

生物质 废塑料 共热解 改性HZSM-5 苯系物

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(11)