首页|玻璃纤维增强聚丙烯材料的高温蠕变变形机理和时间硬化模型

玻璃纤维增强聚丙烯材料的高温蠕变变形机理和时间硬化模型

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材料的抗蠕变性与产品长期服役下的强度、刚度和尺寸变化息息相关,是轻量化技术应用和发展的重要研究方向.为探究玻璃纤维增强聚丙烯材料(PP-GF30)的蠕变变形机理及时间硬化模型,将PP-GF30在一定注塑工艺条件下制备成标准哑铃型样条,通过蠕变试验机进行蠕变性能测试,表征PP-GF30的高温蠕变行为.结果表明,PP-GF30在高温下的拉伸强度和模量与温度呈线性关系,失效模式由纤维断裂向界面破坏演变.高温蠕变变形包含普弹形变、高弹形变和黏性流动,普弹形变和高弹形变与蠕变应力呈线性增长,外力除去后回复;黏性流动与蠕变应力呈指数型增长,外力除去后形变不可回复.时间硬化修正模型为εc=Aσncta+bσc,修正了蠕变应力对时间指数的影响,大大提升了系统精度.
High Temperature Creep Deformation Mechanism and Time Hardening Model of Glass Fiber Reinforced Polypropylene
The creep resistance of materials is closely related to the strength,stiffness,and dimensional changes of products under long-term service,which is an important research direction for the applications and developments of lightweight technology.To investigate the creep deformation mechanism and time hardening model of glass fiber reinforced polypropylene materials(PP-GF30s),PP-GF30s were prepared into standard dumbbell shaped splines under certain injection molding conditions.The creep performance tests were carried out via a creep testing machine,characterizing the sample high-temperature creep behaviors.The results show that the tensile strength and modulus of PP-GF30s at high temperatures exhibit a linear trend with temperature,and the failure mode evolves from fiber fracture to interface failure.High temperature creep deformation includes general elastic deformation,high elastic deformation,and viscous flow.The general elastic deformation and high elastic deformation increase linearly with creep stress,and recover after the external force is removed.Viscous flow and creep stress exhibit exponential growth,and deformation cannot recover after the external force is removed.The time hardening correction model is εc=Aσncta+bσc.The effect of creep stress on the time index is corrected,and the system accuracy is greatly improved.

Glass Fiber Reinforced PolypropyleneCreepViscoelasticityTime Hardening ModelTime Index

陈涛、匡莉、孙刚

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国高材高分子材料产业创新中心有限公司,广东 广州 510663

上海金发科技发展有限公司,上海 201799

玻璃纤维增强聚丙烯 蠕变 黏弹性 时间硬化模型 时间指数

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(12)