首页|负载花色苷淀粉/壳聚糖低共熔溶剂增塑膜的构建及性能

负载花色苷淀粉/壳聚糖低共熔溶剂增塑膜的构建及性能

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本文旨在筛选匹配性能优良的增塑剂品种,制备高性能淀粉/壳聚糖复合薄膜,拓宽食用保鲜膜的应用范围.采用溶液流延法,将壳聚糖与淀粉按一定质量比混合后,加适量的花色苷作为保鲜剂,并添加不同种类的低共熔溶剂,倒入平板流延成膜.低共熔溶剂氢受体为甜菜碱,氢供体为乳酸、柠檬酸和尿素.通过调控低共熔溶剂的质量分数,制备不同类型和功效的复合薄膜.经过力学性能、透水性能、傅里叶红外光谱分析和热稳定性能等表征手段,同时对抗氧化性、自由基清除率与抑菌性进行实验分析,评价复合薄膜的物化特性.结果表明,当低共熔溶剂的氢供体为柠檬酸,添加的质量分数为20%时,复合薄膜的拉伸强度达到42.77 MPa,水蒸气透过系数为1.843×10-11 g.cm/(cm2·s·Pa),自由基清除率为96%,复合薄膜的综合性能最佳.
Construction and Properties of Anthocyanin Starch/Chitosan Eutectic Solvent Plasticized Films
This paper aimed to select plasticizers with excellent performances to prepare high-performance starch/chitosan composite films,broadening the application ranges of edible cling films.Using the solution casting method,chitosan and starch were mixed at a specific mass ratio,an appropriate amount of anthocyanin was added as a preservative,and different types of eutectic solvents were incorporated,then the blends were cast into flat surfaces to form films.The hydrogen bond acceptor in the eutectic solvents was betaine,and the hydrogen bond donors were lactic acid,citric acid,and urea.By adjusting the mass fractions of eutectic solvents,composite films with different types and functions were prepared.The films were characterized by using mechanical properties,water vapor permeability,Fourier transform infrared(FTIR)spectroscopy,and thermal stability analysis.Additionally,antioxidant activity,free radical scavenging rate,and antibacterial properties were experimentally analyzed to evaluate the physicochemical characteristics of the composite films.The results show that when citric acid is used as the hydrogen bond donor in the eutectic solvent and its mass fraction is 20%,the tensile strength of the composite film reaches 42.77 MPa,the water vapor permeability coefficient is 1.843x 10-11 g·cm/(cm2·s·Pa),and the free radical scavenging rate is 96%,showing the best overall performances.

Composite FilmPlasticizerEutectic SolventStarchAntioxidant Property

鲁珏、户彦冰、王田心、代鹏、王浩

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天津科技大学食品科学与工程学院,天津 300457

天津科技大学食品营养与安全国家重点实验室,天津 300457

天津大学机械工程学院,天津 300354

复合薄膜 增塑剂 低共熔溶剂 淀粉 抗氧化性

2024

塑料工业
中蓝晨光化工研究院有限公司

塑料工业

CSTPCD北大核心
影响因子:0.685
ISSN:1005-5770
年,卷(期):2024.52(12)