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生物诱导碳酸钙沉淀在改善土壤侵蚀中的应用

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[目的]雨、雪、波浪、风等作用常会引起土壤侵蚀。生物诱导碳酸钙沉淀技术(MICP/EICP)由于环境友好的特点已成为岩土和地质领域的研究热点之一。为了探究MICP/EICP在土壤抗侵蚀性方面的效果,[方法]介绍了 MICP/EICP的矿化过程,基于现有成果总结了 MICP/EICP改善不同类型土壤侵蚀效果。[结果]结果显示:对于土壤适应性,MICP处理粗砂的无侧限抗压强度和CaCO3含量高于EICP,而在粉细砂中结果相反。对于遇水崩解特性,MICP改性黏土中25 μm以下颗粒质量减少,75~250μm颗粒质量分数增加,团聚体变大,有效降低了黏土、黄土、黏性紫色土崩解速率和崩解率。对于波浪侵蚀特性,随喷洒固化次数由 1增加到4,海岸砂质边坡侵蚀速率呈对数下降,固化18次后,30次潮汐变化下坡角几乎不变。对于切向水流侵蚀特性,1 g/L的黄原胶溶液结合MICP固化2次的样品和0。5 mol/L胶结液结合掺入0。2%纤维所得到的固化土的抗侵蚀性优于单纯高剂量MICP处理的结果。对于风蚀,MICP固化时,0。25 mol/L胶结液可达到抗风蚀效果,而EICP反应较快应加入抑制剂。对于多次干湿和冻融循环侵蚀,MICP/EICP处理试样的强度和侵蚀量都好于未处理试样,EICP处理砂土样的耐久性效果不如MICP明显。[结论]结果表明:MICP适用于粗粒土,生成的CaCO3整体性好;EICP脲酶分子小,工艺简单,可应用于细粒土中,但生成的CaCO3较松散。MICP/EICP作用可有效降低细粒土的遇水崩解特性,有效降低海岸砂质边坡的波浪侵蚀,与纤维或生聚物结合可改善固化土的脆性,抵抗切向水流的侵蚀。低浓度的胶结液配方即可抵抗风蚀。MICP/EICP可提高固化土的耐久性。
Application of biological induced calcium carbonate precipitation in improving soil erosion
[Objective]Rain,snow,waves,and wind often cause soil erosion.The bio-induced calcium carbonate precipitation technology(MICP/EICP)has become one of the research hotspots in the fields of geotechnical and geological engineering due to its environmental friendliness.[Methods]This article introduces the mineralization process of MICP/EICP,and summarizes the improved erosion effects of MICP/EICP on different types of soil based on existing research result.[Results]For soil adaptabili-ty,the unconfined compressive strength and CaCO3 content of MICP-treated coarse sand are higher than those of EICP,while the opposite is true in fine sand.For water-induced disintegration characteristics,the mass of particles below 25 μm in MICP-modi-fied clay decreases,while the mass fraction of particles between 75 and 250 µm increases,[Results]ing in larger aggregates in clay,loess,and sticky purple soil,effectively reducing the disintegration rate and disintegration rate of these soils.For wave ero-sion characteristics,with the increase in the number of spray curing from 1 to 4,the erosion rate of coastal sandy slopes decreases logarithmically.After 18 curing times,the slope angle remains almost unchanged under 30 tidal changes.For the erosion charac-teristics of tangential flow,the erosion resistance of the soil samples treated with 1 g/L xanthan gum solution combined with MICP curing for 2 times and 0.5 mol/L cement solution combined with 0.2%fiber is better than that of the soil samples treated with high-dose MICP alone.For wind erosion,when MICP is cured,0.25 mol/L cement solution can achieve wind erosion resistance,while EICP reacts faster and should be added with inhibitors.For multiple dry-wet and freeze-thaw cycles,the strength and ero-sion amount of MICP/EICP-treated samples are better than those of untreated samples,and the durability effect of EICP-treated sandy soil samples is not as obvious as that of MICP.[Conclusion]MICP is suitable for coarse-grained soil,and the generated CaCO3 has good integrity;EICP has small urease molecules and simple process,and can be applied to fine-grained soil,but the generated CaCO3 is loose.The MICP/EICP effect can effectively reduce the water-induced disintegration characteristics of fine-grained soil,effectively reduce wave erosion of coastal sandy slopes,and improve the brittleness of solidified soil by combining with fibers or biopolymers to resist the erosion of tangential water flow.A low concentration of cementing fluid formula can resist wind erosion.MICP/EICP can improve the durability of solidified soil.

MICPEICPsoil erosioninfluencing factorssoil and water conservationclimate changemechanical proper-tiesCarbon Peaking

耿会岭、赵卫全、赵永刚、杨晓东、于凡

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中国水利水电科学研究院,北京 100038

流域水循环模拟与调控国家重点实验室,北京 100038

中水淮河规划设计研究有限公司,安徽合肥 230006

MICP EICP 土壤侵蚀 影响因素 水土保持 气候变化 力学性能 碳达峰

国家重点研发计划引江济淮公司科研项目中国水科院科研专项

2019YFC1509800YJJH-ZT-ZX-20221130515EM0145B182020

2024

水利水电技术(中英文)
水利部发展研究中心

水利水电技术(中英文)

CSTPCD北大核心
影响因子:0.456
ISSN:1000-0860
年,卷(期):2024.55(3)
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