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TPO和POE增韧改性研究

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以抗冲共聚聚丙烯、均聚聚丙烯为基体树脂,添加一定比例的滑石粉、抗氧剂、增韧剂,利用双螺杆挤压造粒机制备改性材料.通过对比试样熔体流动速率、密度、成型收缩率、拉伸性能、弯曲性能及热性能研究聚烯烃弹性体TPO和POE的增韧效果.实验结果表明:密度无规律变化,变化幅度不大;熔体流动速率减小,TPO下降趋势更大;成型收缩率显著下降,TPO加入更大量后有所回弹;拉伸强度、弯曲强度、负荷热变形温度均减小,POE更加明显;常温悬臂梁缺口冲击强度影响较大,POE的冲击性能是TPO的2倍以上;低温悬臂梁缺口冲击强度缓慢增加.最终得出TPO可以应用于聚丙烯的增韧改性,但只能应用于对韧性要求相对较低的复合材料.
Toughening Modification of Polyolefin Elastomers TPO and POE
Using impact copolymer polypropylene and homopolymer polypropylene as matrix resins,we added a certain proportion of talc powder,antioxidant,and toughening agent,and utilized twin-screw extrusion granulation mechanism to prepare modified materials.On this basis,we studied the toughening effect of polyolefin elastomers TPO and POE by comparing the melt flow rate,density,molding shrinkage,tensile properties,bending properties,and thermal properties of the samples.The experimental results indicate that the density changes irregularly and the magnitude of the change is not significant.The decrease in melt flow rate leads to a greater downward trend in TPO.The molding shrinkage rate significantly decreases,and there is some rebound after adding a larger amount of TPO.The tensile strength,bending strength,and temperature of thermal deformation under load all decrease,and POE becomes more pronounced.The impact strength of room temperature cantilever beams is greatly affected by the notch,and the impact performance of POE is more than twice that of TPO.The impact strength of the low-temperature cantilever beam gap slowly increases.Ultimately,TPO can be applied for toughening modification of polypropylene,but only for composite materials with relatively low toughness requirements.

polypropylenepolyolefinelastomertoughening modificationperformance analysiscomposite materials

王行连、蔡立恒、刘浪、程青青、王晓茹、高芙蓉

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陕西延长中煤榆林能源化工股份有限公司产品研发中心,陕西靖边 718500

聚丙烯 聚烯烃 弹性体 增韧改性 性能分析 复合材料

2024

塑料助剂
南京市化学工业研究设计院有限公司

塑料助剂

CSTPCD
影响因子:0.315
ISSN:1672-6294
年,卷(期):2024.(5)